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2022 Vol.54, Issue 4 Preview Page
Preparation of Lignin Derivatives Substituted with 3,4-dihydroxybenzylamine and Their Application as a Biomaterial with Antioxidant and Ultraviolet Light Blocking Properties

3,4-다이하이드록시벤질아민으로 치환된 리그닌 유도체 제조 및 항산화 & 자외선 차단 특성 바이오소재로 응용

Jin Ho Bae1
,
Ji Won Heo2
,
Yong Sik Kim3†
배진호 1
,
허지원 2
,
김용식 3†
1Tae Kyung Ind. Co., Ltd.
2Department of Paper Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University
3Department of Paper Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University
1태경산업(주) 괴산공장, 사원
2강원대학교 산림환경과학대학 제지공학과, 대학원생
3강원대학교 산림환경과학대학 제지공학과, 교수
†Corresponding author: E-Mail: yongsikk@kangwon.ac.kr (Address: Department of Paper Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon 24341, Republic of Korea)
30 August 2022. pp. 42-56
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Abstract

Epoxy kraft lignin (EKL) was prepared by substituting the hydroxyl groups of kraft lignin with epoxide groups. Subsequently, 3,4-dihydroxybenzylamine (DHBA) was introduced to the prepared EKL substituted with DHBA (EKL-DHBA) to impart antioxidant and ultraviolet (UV) light blocking properties. Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and 1H nuclear magnetic resonance spectroscopy confirmed that the DHBA moiety had been grafted successfully onto the lignin macromolecule. Additionally, 31P NMR analysis revealed that EKL-DHBA had a higher content of phenolic hydroxyl groups than KL, owing to catechol structure substitution. EKL-DHBA/polyvinyl alcohol (PVA) films were prepared and their antioxidant and UV blocking properties were investigated. The antioxidant activity of the film prepared adding 1 wt.% of EKL-DHBA was 93.15%, which was higher than that of ethanol soluble kraft lignin (EL). Furthermore, the EKL-DHBA/PVA film exhibited excellent UV blocking properties of approximately 96.75% –86.12% in UV-B (280-320 nm) and 86.12% in UV-A (280-400 nm) regions. Thus, the UV blocking properties of the EKL-DHBA/PVA film was much higher than that of EL or PVA film. Therefore, EKL-DHBAs with excellent antioxidant and UV blocking properties are potential additives to composite biomaterials.

Keywords
Kraft lignin
DHBA
Antioxidant
UV-blocking
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Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 54
  • No :4
  • Pages :42-56
  • Received Date : 2022-06-29
  • Revised Date : 2022-07-31
  • Accepted Date : 2022-08-01
  • DOI :https://doi.org/10.7584/JKTAPPI.2022.08.54.4.42
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