All Issue

2018 Vol.50, Issue 5 Preview Page
Study on Improvement of Preparation Efficiency of Lignin Rich Micro-Cellulosic Fines

리그닌이 풍부한 셀룰로오스 미세분의 제조 효율 향상

Jung Myoung Lee
,
Eun-Byeol Ahn1
,
Hyo-Seok Choi2
,
Ji-Ae Ryu2
,
Tae-Jin Eom†
이중명
,
안은별 1
,
최효석 2
,
류지애 2
,
엄태진 †
Major in Wood Science and Technology, Department of Wood Science and Technology, School of Forestry, Science and Landscape Architecture, Kyungpook National University, 80 Daehakro, Bukgu, Daegu, 41566
1Agricultural Science and Technology Research Institute, Kyungpook National University, 80 Daehakro, Bukgu, Daegu, 41566
2Department of Wood Science and Technology, Kyungpook National University, 80 Daehakro, Bukgu, Daegu, 41566
경북대학교 산림과학·조경학부 임산공학전공
1경북대학교 농업과학기술연구소
2경북대학교 임산공학과
†Corresponding author: E-Mail: tjeom@knu.ac.kr
30 October 2018. pp. 114-122
PDF XML Citation
Abstract

We compared the characteristics of the three LMCFs (lignin rich micro-cellulosic fines) prepared by microwave irradiation, oil bath treatment and high pressure steam treatment from pine wood powder. The residual lignin contents of the LMCFs prepared by the three methods were almost similar but the yields were different. The microwave irradiation method hydrolyzed the pine wood powder more greatly compared to the other methods. So, the LMCFs prepared by microwave irradiation showed the lowest particle size and the least amount of hydroxyl groups but, showed the highest total crystallinity index. It was found that the LMCFs prepared by the three methods were similar in morphology but different in content of aromatic ring and carbonyl group. Based on these results, LMCFs could be produced efficiently depending on the manufacturing time, energy cost, and uniformity of micronized samples. It was concluded that the high pressure steam treatment method, which produces the uniform production of LMCFs as the purpose, is the optimum micronization method.

Keywords
Chemical micronization
lignin rich micro-cellulosic fines (LMCFs)
microwave irradiation, oil bath-treatment
autoclave-treatment
spectroscopic properties
References

Literature Cited

1
M. Stöcker, Angewandte Chemie International Edition, Biofuels and biomass-to-liquid fuels in the biorefinery: catalytic conversion of lignocellulosic biomass using porous materials, 47(48); 9200-9211 (2008)

Stöcker, M., Biofuels and biomass-to-liquid fuels in the biorefinery: catalytic conversion of lignocellulosic biomass using porous materials, Angewandte Chemie International Edition, 47(48):9200-9211 (2008).

2
N. Doassans-Carrère, J. H. Ferrasse, O. Boutin, G. Mauviel and J. Lédé, Energy & Fuels, Comparative study of biomass fast pyrolysis and direct liquefaction for bio-oils production: products yield and characterizations, 28(8); 5103-5111 (2014)

Doassans-Carrère, N., Ferrasse, J. H., Boutin, O., Mauviel, G., and Lédé, J., Comparative study of biomass fast pyrolysis and direct liquefaction for bio-oils production: products yield and characterizations, Energy & Fuels, 28(8):5103-5111 (2014).

3
H. Ramsurn and R. B. Gupta, Energy & Fuels, Production of biocrude from biomass by acidic subcritical water followed by alkaline supercritical water two-step liquefaction, 26(4); 2365-2375 (2012)

Ramsurn, H. and Gupta, R. B., Production of biocrude from biomass by acidic subcritical water followed by alkaline supercritical water two-step liquefaction, Energy & Fuels, 26(4):2365-2375 (2012).

10.1021/ef2020414
4
S. Karagöz, T. Bhaskar, A. Muto, Y. Sakata and M. A. Uddin, Energy & fuels, Low-temperature hydrothermal treatment of biomass: effect of reaction parameters on products and boiling point distributions, 18(1); 234-241 (2004)

Karagöz, S., Bhaskar, T., Muto, A., Sakata, Y., and Uddin, M. A., Low-temperature hydrothermal treatment of biomass: effect of reaction parameters on products and boiling point distributions, Energy & fuels, 18(1):234-241 (2004).

5
A. Demirbaş, Energy conversion and Management, Biomass resource facilities and biomass conversion processing for fuels and chemicals, 42(11); 1357-1378 (2001)

Demirbaş, A., Biomass resource facilities and biomass conversion processing for fuels and chemicals, Energy conversion and Management, 42(11):1357-1378 (2001).

6
C. H. Zhou, X. Xia, C. X. Lin, D. S. Tong and J. Beltramini, Chemical Society Reviews, Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels, 40(11); 5588-5617 (2011)

Zhou, C. H., Xia, X., Lin, C. X., Tong, D. S., and Beltramini, J., Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels, Chemical Society Reviews, 40(11):5588-5617 (2011).

10.1039/c1cs15124j
7
J. P. Lange, Biofuels, Bioproducts and Biorefining: Innovation for a Sustainable Economy, Lignocellulose conversion: an introduction to chemistry, process and economics, 1(1); 39-48 (2007)

Lange, J. P., Lignocellulose conversion: an introduction to chemistry, process and economics, Biofuels, Bioproducts and Biorefining: Innovation for a Sustainable Economy, 1(1):39- 48 (2007).

10.1002/bbb.7
8
A. Demirbas, Energy Sources, Part A, Liquefaction of biomass using glycerol, 30(12); 1120-1126 (2008)

Demirbas, A., Liquefaction of biomass using glycerol, Energy Sources, Part A 30(12):1120-1126 (2008).

10.1080/15567030601100654
9
A. Demirbas, Energy Conversion and Management, Biorefineries: current activities and future developments, 50(11); 2782-2801 (2009)

Demirbas, A., Biorefineries: current activities and future developments, Energy Conversion and Management, 50(11): 2782-2801 (2009).

10.1016/j.enconman.2009.06.035
10
A. Kržan and M. Kunaver, Journal of Applied Polymer Science, Microwave heating in wood liquefaction, 101(2); 1051-1056 (2006)

Kržan, A. and Kunaver, M., Microwave heating in wood liquefaction, Journal of Applied Polymer Science, 101(2):1051-1056 (2006).

11
A. Kržan and E. Žagar, Bioresource Technology, Microwave driven wood liquefaction with glycols, 100(12); 3143-3146 (2009)

Kržan, A. and Žagar, E., Microwave driven wood liquefaction with glycols, Bioresource Technology, 100(12):3143-3146 (2009).

12
C. O. Kappe, Chemical Society Reviews, Microwave dielectric heating in synthetic organic chemistry, 37(6); 1127-1139 (2008)

Kappe, C. O., Microwave dielectric heating in synthetic organic chemistry, Chemical Society Reviews, 37(6):1127-1139 (2008).

13
K. J. Kim, G. B. Nah, J. A. Ryu and T. J. Eom, Journal of Korea TAPPI, Preparation of lignin rich micro-cellulose fines (LMCFs) by chemical micronization method and characteristics of LMCFs handsheet, 49(3); 109-117 (2017)

Kim, K. J., Nah, G. B., Ryu, J. A., and Eom, T. J., Preparation of lignin rich micro-cellulose fines (LMCFs) by chemical micronization method and characteristics of LMCFs handsheet, Journal of Korea TAPPI, 49(3):109-117 (2017).

10.7584/jktappi.2017.06.49.3.109
14
G. B. Nah, J. A. Ryu, J. M. Lee and T. J. Eom, Journal of Korea TAPPI, Chemical micronization of woody biomass using the microwave, 49(4); 150-158 (2017)

Nah, G. B., Ryu, J. A., Lee, J. M., and Eom, T. J., Chemical micronization of woody biomass using the microwave, Journal of Korea TAPPI, 49(4):150-158 (2017).

10.7584/jktappi.2017.08.49.4.150
15
J. Ṧiroký, R. S. Blackburn, T. Bechtold, J. Taylor and P. White, Cellulose, Attenuated total reflectance Fourier-transform Infrared spectroscopy analysis of crystallinity changes in lyocell following continuous treatment with sodium hydroxide, 17(1); 103-115 (2010)

Ṧiroký, J., Blackburn, R. S., Bechtold, T., Taylor, J., and White, P., Attenuated total reflectance Fourier-transform Infrared spectroscopy analysis of crystallinity changes in lyocell following continuous treatment with sodium hydroxide, Cellulose, 17(1):103-115 (2010).

16
A. Savitzky and M. J. E. Golay, Analytical Chemistry, Smoothing and differentiation of data simplified least squares procedures, 36(8); 1627-1639 (1964)

Savitzky, A. and Golay, M. J. E., Smoothing and differentiation of data simplified least squares procedures, Analytical Chemistry, 36(8):1627-1639 (1964).

17
T. M. Jones and P. Albersheim, Plant Physiology, A gas chromatographic method for the determination of aldose and uronic acid constituents of plant cell wall polysaccharides, 49(6); 926-936 (1972)

Jones, T. M. and Albersheim, P., A gas chromatographic method for the determination of aldose and uronic acid constituents of plant cell wall polysaccharides, Plant Physiology, 49(6):926-936 (1972).

10.1104/pp.49.6.926
18
X. Y. Huang, F. Li, J. L. Xie, C. F. De Hoop, C. Y. Hse, J. Q. Qi and H. Xiao, Bioresources, Microwave-assisted liquefaction of rape straw for the production of bio-oils, 12(1); 1968-1981 (2017)

Huang, X. Y., Li, F., Xie, J. L., De Hoop, C. F., Hse, C. Y., Qi, J. Q., and Xiao, H., Microwave-assisted liquefaction of rape straw for the production of bio-oils, Bioresources, 12(1):1968-1981 (2017).

10.15376/biores.12.1.1968-1981
19
G. Li, C. Hse and T. Qin, Journal of Forest Research, Wood liquefaction with phenol by microwave heating and FTIR evaluation, 26(4); 1043-1048 (2015)

Li, G., Hse, C., and Qin, T., Wood liquefaction with phenol by microwave heating and FTIR evaluation, Journal of Forest Research, 26(4):1043-1048 (2015).

10.1007/s11676-015-0114-0
20
U. Müller, M. Rätzsch, M. Schwanninger, M. Steiner and H. Zöbl, Journal of Photochemistry and Photobiology B: Biology, Yellowing and IR-changes of spruce wood as result of UV-irradiation, 69(2); 97-105 (2003)

Müller, U., Rätzsch, M., Schwanninger, M., Steiner, M., and Zöbl, H., Yellowing and IR-changes of spruce wood as result of UV-irradiation, Journal of Photochemistry and Photobiology B: Biology, 69(2):97-105 (2003).

21
X. Colom, F. Carrillo, F. Nogués and P. Garriga, Polymer Degradation and Stability, Structural analysis of photodegraded wood by means of FTIR spectroscopy, 80(3); 543-549 (2003)

Colom, X., Carrillo, F., Nogués, F., and Garriga, P., Structural analysis of photodegraded wood by means of FTIR spectroscopy, Polymer Degradation and Stability 80(3):543-549 (2003).

10.1016/s0141-3910(03)00051-x
22
M. Schwanninger, J. C. Rodrigues, H. Pereira and B. Hinterstoisser, Vibrational Spectroscopy, Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose, 36(1); 23-40 (2004)

Schwanninger, M., Rodrigues, J. C., Pereira, H., and Hinterstoisser, B., Effects of short-time vibratory ball milling on the shape of FT-IR spectra of wood and cellulose, Vibrational Spectroscopy, 36(1):23-40 (2004).

10.1016/j.vibspec.2004.02.003
23
K. J. Kim and T. J. Eom, Journal of Korea TAPPI, Study on the aging characteristics of paper with principal component analysis, 48(6); 144-149 (2016)

Kim, K. J. and Eom, T. J., Study on the aging characteristics of paper with principal component analysis, Journal of Korea TAPPI, 48(6):144-149 (2016).

10.7584/jktappi.2016.12.48.6.144
Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 50
  • No :5
  • Pages :114-122
  • Received Date : 2018-10-05
  • Revised Date : 2018-10-17
  • Accepted Date : 2018-10-18
  • DOI :https://doi.org/10.7584/JKTAPPI.2018.10.50.5.114
Journal Informaiton Journal of Korea TAPPI Journal of Korea TAPPI
Online Submission
  • scopus
  • NRF
  • KOFST
  • crossref crossmark
  • crossref cited-by
  • crosscheck
  • orcid
Journal Informaiton Journal Informaiton - close