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2018 Vol.50, Issue 5 Preview Page
Characteristics of Cellulose Nanofibril Produced after Quaternary Amine Pretreatment

아민화 전처리로 제조된 셀룰로오스 나노섬유의 특성

Woo-Yong Song
,
Soyoung Juhn1
,
Soo-Jeong Shin1†
송우용
,
전소영 1
,
신수정 1†
Department of Wood and Paper Science, Chungbuk National University, Cheongju, 28644
1Nature CosTech Inc., Cheongju, 28578
충북대학교 목재종이과학과
1네이처코스텍 주식회사
†Corresponding author: E-Mail: soojshin@cbnu.ac.kr
30 October 2018. pp. 107-113
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Abstract

Cellulose nanofibrils produced after quaternary amine pretreatment were investigated as basic characteristics of CNF with nanoparticle size, viscosity, and rheological properties. With DS 0.1 (C-CNF1), width of cellulose nanofibril was 8.1-14.1 nm compared with width of 3.9-9.5 nm with DS 0.3 (C-CNF2), which had narrower width distribution than carboxymethyl pretreated cellulose nanofibril (DS 0.3, width range: 3.1-20.6 nm). There was no significant difference in length of CNF regardless of pretreatment method or different degree of substitution. In viscosity, carboxymethylated CNF had higher than quaternary amine treated CNF due to different affinity to aqueous medium with different functional group. Quaternary aminated CNF had gel-like structure but there was no expulsion of water (syneresis), which syneresis is the characteristics of carboxymethylated CNF.

Keywords
Cellulose nanofibril
quaternized amination
cellulose nanofibril size
viscosity
rheological properties
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Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 50
  • No :5
  • Pages :107-113
  • Received Date : 2018-10-04
  • Revised Date : 2018-10-17
  • Accepted Date : 2018-10-18
  • DOI :https://doi.org/10.7584/JKTAPPI.2018.10.50.5.107
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