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2021 Vol.53, Issue 6 Preview Page
Impact of Carboxymethylation Pretreatment on Bleached Rice Hull Nanofiber by Grinding

표백왕겨의 그라인딩 처리에 의한 셀룰로오스 나노 섬유 제조 시 카르복시메틸화 전처리가 미치는 영향

XiangLin Cao1
,
Seo-Kyoung Lim2
,
Woo-Yong Song1
,
Soo-Jeong Shin3†
,
Hyun-A Seong4‡
CaoXiangLin 1
,
임서경 2
,
송우용 1
,
신수정 3†
,
성현아 4‡
1Department of Forest Products, Graduate School, Chungbuk National University
2Nature Costech Inc.
3Department of Wood & Paper Science, Chungbuk National University
4Department of Biochemistry, Chungbuk National University
1충북대학교 대학원 임산공학전공, 대학원생
2네이처코스텍(주), 연구원
3충북대학교 목재종이과학과, 교수
4충북대학교 생화학과, 교수
†Corresponding author: E-Mail: soojshin@cbnu.ac.kr (Address: Department of Wood & Paper Science, Chungbuk National University, Cheongju, 28644, Republic of Korea)
‡Co-corresponding Author: E-Mail: haseong@cbnu.ac.kr (Address: Department of Biochemistry, Chungbuk National University, Cheongju, 28644, Republic of Korea)
30 December 2021. pp. 146-156
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Abstract

Rice hull is a agricultural byproducts that can be a raw material for cellulose nanofiber. We produced cellulose nanofiber from rice hulls through chlorine dioxide bleaching followed by carboxymethylation and nano-grinding. We investigated the degree of pre-treament by zeta-potential, and 1H-NMR spectroscopy. The characterstics of cellulose nanofiber was measured by particle size and water holding ability.

After bleaching, lignin in rice hull was removed and the lignin content of bleached rice hull decreased from 25.8% to not detected level. With carboxymethylation pretreatment, zeta potential of bleached rice hull was increased from –47.2 mV for no pretreated to –49.1 mV - –55.8 mV with different degree of carboxymethylation. Size of cellulose nanofibril was 2.5-122.6 nm and 160-866 nm in length. With increasing carboxymethylation in pretreatment led to thinner width of cellulose nanofibril. Water holding properties of cellulose nanofibril varied from 940% to 2000% with different DS of pretreatment and different number of grinding.

Keywords
Rice hull
carboxymethylation
grinding
cellulose nanofiber
water retention value
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Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 53
  • No :6
  • Pages :146-156
  • Received Date : 2021-12-08
  • Revised Date : 2021-12-27
  • Accepted Date : 2021-12-29
  • DOI :https://doi.org/10.7584/JKTAPPI.2021.12.53.6.146
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