All Issue

2026 Vol.58, Issue 4

Review

30 August 2026. pp. 5-17
Abstract
References
1

Scott, G. M., Abubakr, S., & Smith, A. (1995, May). Sludge characteristics and disposal alternatives for the pulp and paper industry. Paper presented at International Environmental Conference, Atlanta, GA, USA.

2

US EPA. (2017). Paper and paperboard: Material-specific data. Retrieved October 23, 2025, from https://www.epa.gov/facts-and-figures-about-materials-waste-and-recycling/paper-and-paperboard-material-specific-data.

3

Bajpai, P. (2015). Management of pulp and paper mill waste. Springer International Publishing.

10.1007/978-3-319-11788-1
4

Guan, W., Shi, S., Tu, M., & Lee, Y. Y. (2016). Acetone–butanol–ethanol production from Kraft paper mill sludge by simultaneous saccharification and fermentation. Bioresource Technology, 200, 713-721.

10.1016/j.biortech.2015.10.102
5

Monte, M. C., Fuente, E., Blanco, A., & Negro, C. (2009). Waste management from pulp and paper production in the European Union. Waste Management, 29(1), 293-308.

10.1016/j.wasman.2008.02.002
6

Wajima, T., Haga, M., Kuzawa, K., Ishimoto, H., Tamada, O., Ito, K., Nishiyama, T., Downs, R. T., & Rakovan, J. F. (2006). Zeolite synthesis from paper sludge ash at low temperature (90 °C) with addition of diatomite. Journal of Hazardous Materials, 132(2-3), 244-252.

10.1016/j.jhazmat.2005.09.045
7

Kim, M.-J., & Kim, D. (2018). Maximization of CO2 storage for various solvent types in indirect carbonation using paper sludge ash. Environmental Science and Pollution Research, 25(30), 30101-30109.

10.1007/s11356-018-2970-6
8

Hubbe, M. A., & Gill, R. A. (2016). Fillers for papermaking: A review of their properties, usage practices, and their mechanistic role. BioResources, 11(1), 2886-2963.

10.15376/biores.11.1.Hubbe
9

Mahmood, T., & Elliott, A. (2006). A review of secondary sludge reduction technologies for the pulp and paper industry. Water Research, 40(11), 2093-2112.

10.1016/j.watres.2006.04.001
10

Chen, H., Han, Q., Daniel, K., Venditti, R., & Jameel, H. (2014). Conversion of industrial paper sludge to ethanol: Fractionation of sludge and its impact. Applied Biochemistry and Biotechnology, 174(6), 2096-2113.

10.1007/s12010-014-1083-z
11

Fan, Z., South, C., Lyford, K., Munsie, J., van Walsum, P., & Lynd, L. R. (2003). Conversion of paper sludge to ethanol in a semicontinuous solids-fed reactor. Bioprocess and Biosystems Engineering, 26(2), 93-101.

10.1007/s00449-003-0337-x
12

Gomes, D., Domingues, L., & Gama, M. (2016). Valorizing recycled paper sludge by a bioethanol production process with cellulase recycling. Bioresource Technology, 216, 637-644.

10.1016/j.biortech.2016.06.004
13

Budhavaram, N. K., & Fan, Z. (2009). Production of lactic acid from paper sludge using acid-tolerant, thermophilic Bacillus coagulans strains. Bioresource Technology, 100(23), 5966-5972.

10.1016/j.biortech.2009.01.080
14

Marques, S., Santos, J. A. L., Gírio, F. M., & Roseiro, J. C. (2008). Lactic acid production from recycled paper sludge by simultaneous saccharification and fermentation. Biochemical Engineering Journal, 41(3), 210-216.

10.1016/j.bej.2008.04.018
15

Khalili, N. R., Vyas, J. D., Weangkaew, W., Westfall, S. J., Parulekar, S. J., & Sherwood, R. (2002). Synthesis and characterization of activated carbon and bioactive adsorbent produced from paper mill sludge. Separation and Purification Technology, 26(2-3), 295-304.

10.1016/S1383-5866(01)00184-8
16

Chen, M., Zheng, Y., Zhou, X., Li, L., Wang, S., Zhao, P., Lu, L., & Cheng, X. (2019). Recycling of paper sludge powder for achieving sustainable and energy-saving building materials. Construction and Building Materials, 229, 116874.

10.1016/j.conbuildmat.2019.116874
17

Cusidó, J. A., Cremades, L. V., Soriano, C., & Devant, M. (2015). Incorporation of paper sludge in clay brick formulation: Ten years of industrial experience. Applied Clay Science, 108, 191-198.

10.1016/j.clay.2015.02.027
18

Kádár, Z., De Vrije, T., Budde, M. A. W., Szengyel, Z., Réczey, K., & Claassen, P. A. M. (2003). Hydrogen production from paper sludge hydrolysate. Applied Biochemistry and Biotechnology, 107(1-3), 557-566.

10.1385/ABAB:107:1-3:557
19

Mendes, C. V. T., Rocha, J. M. S., & Carvalho, M. G. V. S. (2014). Valorization of residual streams from pulp and paper mills: Pretreatment and bioconversion of primary sludge to bioethanol. Industrial & Engineering Chemistry Research, 53(50), 19398-19404.

10.1021/ie503021y
20

Gurram, R. N., Al-Shannag, M., Lecher, N. J., Duncan, S. M., Singsaas, E. L., & Alkasrawi, M. (2015). Bioconversion of paper mill sludge to bioethanol in the presence of accelerants or hydrogen peroxide pretreatment. Bioresource Technology, 192, 529-539.

10.1016/j.biortech.2015.06.010
21

Zhu, S., Sui, J., Liu, Y., Ye, S., Wang, C., Huo, M., & Yu, Y. (2019). Effects of washing, autoclaving, and surfactants on the enzymatic hydrolysis of negatively valued paper mill sludge for sugar production. Energy & Fuels, 33(2), 1219-1226.

10.1021/acs.energyfuels.8b03586
22

Park, H., Cruz, D., Tiller, P., Johnson, D. K., Mittal, A., Jameel, H., Venditti, R., & Park, S. (2022). Effect of ash in paper sludge on enzymatic hydrolysis. Biomass and Bioenergy, 165, 106567.

10.1016/j.biombioe.2022.106567
23

Yin, B., & Chen, H. (2010). Effect of the ash on enzymatic hydrolysis of steam-exploded rice straw. Bioresource Technology, 101(23), 9114-9119.

10.1016/j.biortech.2010.07.033
24

He, Y., Fang, Z., Zhang, J., Li, X., & Bao, J. (2014). De-ashing treatment of corn stover improves the efficiencies of enzymatic hydrolysis and consequent ethanol fermentation. Bioresource Technology, 169, 552-558.

10.1016/j.biortech.2014.06.088
25

Chen, H., Han, Q., Venditti, R. A., & Jameel, H. (2015). Enzymatic hydrolysis of pretreated newspaper having high lignin content for bioethanol production. BioResources, 10(3), 4077-4098.

10.15376/biores.10.3.4077-4098
26

Feather, M. S., & Harris, J. F. (1973). Dehydration reactions of carbohydrates. In R. S. Tipson & D. Horton (Eds.), Advances in carbohydrate chemistry and biochemistry (Vol. 28, pp. 161-224). Academic Press.

10.1016/S0065-2318(08)60383-2
27

Zhao, H., Holladay, J. E., Brown, H., & Zhang, Z. C. (2007). Metal chlorides in ionic liquid solvents convert sugars to 5-hydroxymethylfurfural. Science, 316(5831), 1597-1600.

10.1126/science.1141199
28

Pidko, E. A., Degirmenci, V., van Santen, R. A., & Hensen, E. J. M. (2010). Coordination properties of ionic liquid-mediated chromium(II) and copper(II) chlorides and their complexes with glucose. Inorganic Chemistry, 49(21), 10081-10091.

10.1021/ic101402r
29

van Putten, R.-J., van der Waal, J. C., de Jong, E., Rasrendra, C. B., Heeres, H. J., & de Vries, J. G. (2013). Hydroxymethylfurfural, a versatile platform chemical made from renewable resources. Chemical Reviews, 113(3), 1499-1597.

10.1021/cr300182k
30

Qian, X. (2012). Mechanisms and energetics for Brønsted acid-catalyzed glucose condensation, dehydration and isomerization reactions. Topics in Catalysis, 55(3-4), 218-226.

10.1007/s11244-012-9790-6
31

Yang, G., Pidko, E. A., & Hensen, E. J. M. (2012). Mechanism of Brønsted acid-catalyzed conversion of carbohydrates. Journal of Catalysis, 295, 122-132.

10.1016/j.jcat.2012.08.002
32

Patil, S. K. R., & Lund, C. R. F. (2011). Formation and growth of humins via aldol addition and condensation during acid-catalyzed conversion of 5-hydroxymethylfurfural. Energy & Fuels, 25(10), 4745-4755.

10.1021/ef2010157
33

Tsilomelekis, G., Orella, M. J., Lin, Z., Cheng, Z., Zheng, W., Nikolakis, V., & Vlachos, D. G. (2016). Molecular structure, morphology and growth mechanisms and rates of 5-hydroxymethyl furfural (HMF) derived humins. Green Chemistry, 18(7), 1983-1993.

10.1039/C5GC01938A
34

Gallo, J. M. R., Alonso, D. M., Mellmer, M. A., & Dumesic, J. A. (2013). Production and upgrading of 5-hydroxymethylfurfural using heterogeneous catalysts and biomass-derived solvents. Green Chemistry, 15(1), 85-90.

10.1039/C2GC36536G
35

Chheda, J. N., & Dumesic, J. A. (2007). An overview of dehydration, aldol-condensation and hydrogenation processes for production of liquid alkanes from biomass-derived carbohydrates. Catalysis Today, 123(1-4), 59-70.

10.1016/j.cattod.2006.12.006
36

Ershova, O., Nieminen, K., & Sixta, H. (2017). The role of various chlorides on xylose conversion to furfural: Experiments and kinetic modeling. ChemCatChem, 9(15), 3031-3040.

10.1002/cctc.201700269
37

Enslow, K. R., & Bell, A. T. (2015). The role of metal halides in enhancing the dehydration of xylose to furfural. ChemCatChem, 7(3), 479-489.

10.1002/cctc.201402842
38

Lin, Q., Zhan, Q., Li, R., Liao, S., Ren, J., Peng, F., & Li, L. (2021). Solvent effect on xylose-to-furfural reaction in biphasic systems: Combined experiments with theoretical calculations. Green Chemistry, 23(21), 8510-8518.

10.1039/D1GC02812J
39

Zhang, L., Yu, H., Wang, P., Dong, H., & Peng, X. (2013). Conversion of xylan, D-xylose and lignocellulosic biomass into furfural using AlCl3 as catalyst in ionic liquid. Bioresource Technology, 130, 110-116.

10.1016/j.biortech.2012.12.018
40

Yemiş, O., & Mazza, G. (2011). Acid-catalyzed conversion of xylose, xylan and straw into furfural by microwave-assisted reaction. Bioresource Technology, 102(15), 7371-7378.

10.1016/j.biortech.2011.04.050
41

Choudhary, V., Sandler, S. I., & Vlachos, D. G. (2012). Conversion of xylose to furfural using Lewis and Brønsted acid catalysts in aqueous media. ACS Catalysis, 2(9), 2022-2028.

10.1021/cs300265d
42

Binder, J. B., Blank, J. J., Cefali, A. V., & Raines, R. T. (2010). Synthesis of furfural from xylose and xylan. ChemSusChem, 3(11), 1268-1272.

10.1002/cssc.20100018120836121PMC4445733
43

Marcotullio, G., & de Jong, W. (2011). Furfural formation from D-xylose: The use of different halides in dilute aqueous acidic solutions allows for exceptionally high yields. Carbohydrate Research, 346(11), 1291-1293.

10.1016/j.carres.2011.04.036
44

Weingarten, R., Cho, J., Conner, W. C., Jr., & Huber, G. W. (2010). Kinetics of furfural production by dehydration of xylose in a biphasic reactor with microwave heating. Green Chemistry, 12(8), 1423-1429.

10.1039/c003459b
45

Mittal, A., Black, S. K., Vinzant, T. B., O’Brien, M., Tucker, M. P., & Johnson, D. K. (2017). Production of furfural from process-relevant biomass-derived pentoses in a biphasic reaction system. ACS Sustainable Chemistry & Engineering, 5(7), 5694-5701.

10.1021/acssuschemeng.7b00215
46

Rosatella, A. A., Simeonov, S. P., Frade, R. F. M., & Afonso, C. A. M. (2011). 5-Hydroxymethylfurfural (HMF) as a building block platform: Biological properties, synthesis and synthetic applications. Green Chemistry, 13(4), 754-793.

10.1039/c0gc00401d
47

Ordomsky, V. V., Sushkevich, V. L., Schouten, J. C., van der Schaaf, J., & Nijhuis, T. A. (2013). Glucose dehydration to 5-hydroxymethylfurfural over phosphate catalysts. Journal of Catalysis, 300, 37-46.

10.1016/j.jcat.2012.12.028
48

Guan, J., Cao, Q., Guo, X., & Mu, X. (2011). The mechanism of glucose conversion to 5-hydroxymethylfurfural catalyzed by metal chlorides in ionic liquid: A theoretical study. Computational and Theoretical Chemistry, 963(2-3), 453-462.

10.1016/j.comptc.2010.11.012
49

Hu, S., Zhang, Z., Song, J., Zhou, Y., & Han, B. (2009). Efficient conversion of glucose into 5-hydroxymethylfurfural catalyzed by a common Lewis acid SnCl4 in an ionic liquid. Green Chemistry, 11(11), 1746-1749.

10.1039/b914601f
50

Takagaki, A., Ohara, M., Nishimura, S., & Ebitani, K. (2009). A one-pot reaction for biorefinery: Combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides. Chemical Communications, 45(41), 6276-6278.

10.1039/b914087e
51

Ohara, M., Takagaki, A., Nishimura, S., & Ebitani, K. (2010). Syntheses of 5-hydroxymethylfurfural and levoglucosan by selective dehydration of glucose using solid acid and base catalysts. Applied Catalysis A: General, 383(1-2), 149-155.

10.1016/j.apcata.2010.05.040
52

Rezayan, A., Wang, K., Nie, R., Lu, T., Wang, J., Zhang, Y., & Xu, C. C. (2022). Synthesis of bifunctional tin-based silica–carbon catalysts, Sn/KIT-1/C, with tunable acid sites for the catalytic transformation of glucose into 5-hydroxymethylfurfural. Chemical Engineering Journal, 429, 132261.

10.1016/j.cej.2021.132261
53

Meier, S. (2020). Mechanism and malleability of glucose dehydration to HMF: Entry points and water-induced diversions. Catalysis Science & Technology, 10(6), 1724-1730.

10.1039/C9CY02567G
54

Xu, H., Cui, X., Bi, Z., Guo, Y., Xu, D., Kong, L., & Miao, P. (2026). Synergy of wettability and acidity in carbon-based acid catalysts for efficient conversion of glucose to 5-hydroxymethylfurfural. Catalysis Science & Technology, 16(8), 2703-2715.

10.1039/D5CY01543J
55

Cruz, D., Park, H., Tiller, P., Kumar, A., Gonzalez, R., Mittal, A., Johnson, D. K., & Park, S. (2025). Catalytic conversion of paper sludge carbohydrates to jet fuel range hydrocarbons: Process optimization and techno-economic analysis. Chemical Engineering Journal, 507, 160622.

10.1016/j.cej.2025.160622
56

Lan, K., Cruz, D., Li, J., Agyei Boakye, A. A., Park, H., Tiller, P., Mittal, A., Johnson, D. K., Park, S., & Yao, Y. (2024). Life-cycle assessment of sustainable aviation fuel derived from paper sludge. ACS Sustainable Chemistry & Engineering, 12(22), 8379-8390.

10.1021/acssuschemeng.4c00795
Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 58
  • No :4
  • Pages :5-17
  • Received Date : 2026-08-05
  • Revised Date : 2026-08-20
  • Accepted Date : 2026-08-20