All Issue

2017 Vol.49, Issue 3 Preview Page
Preparation of Lignin rich Micro-Cellulose Fines (LMCFs) by Chemical Micronization Method and Characteristics of LMCFs Handsheet

화학적 미분화에 의한 리그닌이 풍부한 마이크로셀룰로오스 미세분의 제조 및 수초 특성

Kang-Jae Kim
,
Gi-Baek Nah1
,
Ji-Ae Ryu1
,
Tae-Jin Eom2†
김강재
,
나기백 1
,
류지애 1
,
엄태진 2†
Agricultural Science and Technology Research Institute, Kyungpook National University, Daegu, 41566
1Department of Wood Science and Technology, Kyungpook National University, Daegu, 41566
2Major in Wood Science and Technology, Department of Wood Science and Technology, School of Forestry, Science and Landscape Architecture, Kyungpook National University, Daegu, 41566
경북대학교 농업과학기술연구소
1경북대학교 임산공학과
2경북대학교 산림과학·조경학부 임산공학전공
†Corresponding author: E-Mail: tjeom@knu.ac.kr
30 June 2017. pp. 109-117
PDF XML Citation
Abstract

In this study, chemical micronization method was used to produce (lignin rich microcellulose fines (LMCFs) of 10% lignin contents. The handsheets of containing 5% LMCFs were prepared and analyzed their physical characteristics. The morphology of LMCFs were changed according to the grinder (Super Masscollider) passing number. After passing 10 times through the grinder, the shape of LMCFs became similar to those of secondary fines. The drainage time of LMCFs was much shorter than that of MFCs. The tensile index gradually increased with the grinding passing number of LMCFs. The tensile index of the handsheet containing LMCFs of 10 passing number was 38.8 N·m/g, that was 33% improvement from the handsheet without LMCFs. The brightness of the handsheet containing LMCFs was improved in proportional to the grinder passing number.

Keywords
Lignin rich Micro-Cellulose Fines (LMCFs)
chemical micronization
grinding
high-boiling point solvent
fines
References

Literature Cited

1
B. Krogerus, L. Eriksson, A. Sundberg, J. Mosbye, A. Ahlroth, I. Östlund and L. Sjöström, Fines in closed circuits - Final report, SCAN Forsk report 740; 7-11, Espoo, Finland. KCL. (2002)

Krogerus, B., Eriksson, L., Sundberg, A., Mosbye, J., Ahlroth, A., Östlund, I., and Sjöström, L., Fines in closed circuits - Final report, SCAN Forsk report 740, KCL, Espoo, Finland, 7-11 (2002).

2
T. Taipale, Interactions of microfibrillated cellulose and cellulosic fines with cationic polyelectrolytes; 5-22, Finland. Aalto University School of Science and Technology. (2010)

Taipale, T., Interactions of microfibrillated cellulose and cellulosic fines with cationic polyelectrolytes, Doctoral Dissertation, Aalto University School of Science and Technology, Finland, 5-22 (2010).

3
T. Tailale, M. Österberg, A. Nykänen, J. Ruokolainen and J. Laine, Cellulose, Effect of microfibrillated cellulose and fines on the grainage of kraft pulp suspension and paper strength, 17(5); 1005-1020 (2010)

Tailale, T., Österberg, M., Nykänen, A., Ruokolainen, J., and Laine, J., Effect of microfibrillated cellulose and fines on the grainage of kraft pulp suspension and paper strength, Cellulose 17(5):1005-1020 (2010).

4
A. Dufresne, Materialstory, Nanocellulose: A new ageless bionanomaterial, 16(6); 220-227 (2013)

Dufresne, A., Nanocellulose: A new ageless bionanomaterial, Materialstory 16(6):220-227 (2013).

10.1016/j.mattod.2013.06.004
5
M. Jorfi and E. J. Foster, Journal of Applied Polymer Science, Recent advances in nanocellulose for biomedical applocations, 13241719(141-19) (2015)

Jorfi, M. and Foster, E. J., Recent advances in nanocellulose for biomedical applocations, Journal of Applied Polymer Science 132(14): 41719(1-19) (2015).

6
J. Y. Lee, C. H. Kim, E. H. Kim, T. U. Park, J. P. Jeon and S. Y. Kim, Journal of Korea TAPPI, Evaluation of electron beam irradiation as new pretreatment for cellulose nanofibril production, 48(4); 99-106 (2016)

Lee, J. Y., Kim, C. H., Kim, E. H., Park, T. U., Jeon, J. P., and Kim, S. Y., Evaluation of electron beam irradiation as new pretreatment for cellulose nanofibril production, Journal of Korea TAPPI 48(4):99-106 (2016).

10.7584/jktappi.2016.08.48.4.99
7
J. Lee, K. Sim, K. Sim and H. J. Youn, Journal of Korea TAPPI, Strengthening effect of surface treatment of cellulose nanofibrils on aged paper, 48(6); 123-130 (2016)

Lee, J., Sim, K., Sim, K., and Youn, H. J., Strengthening effect of surface treatment of cellulose nanofibrils on aged paper, Journal of Korea TAPPI 48(6):123-130 (2016).

10.7584/jktappi.2016.12.48.6.123
8
E. Bahar, N. Ucar, A. Onen, Y. Wang, M. Oksuz, O. Ayaz, M. Ucar and A. Demir, Journal of Applied Polymer Science, Thermal and mechanical properties of polypropylene nanocomposite materials reinforced with cellulose nano whiskers, 125(4); 2882-2889 (2012)

Bahar, E., Ucar, N., Onen, A., Wang, Y., Oksuz, M., Ayaz, O., Ucar, M., and Demir, A., Thermal and mechanical properties of polypropylene nanocomposite materials reinforced with cellulose nano whiskers, Journal of Applied Polymer Science 125(4):2882-2889 (2012).

10.1002/app.36445
9
M. Nogi, S. Iwamoto, A. N. Nakagaito and H. Yano, Advanced Materials, Optically transparent nanofiber paper, 21(16); 1595-1598 (2009)

Nogi, M., Iwamoto, S., Nakagaito, A. N., and Yano, H., Optically transparent nanofiber paper, Advanced Materials 21(16):1595-1598 (2009).

10.1002/adma.200803174
10
J. M. Lee, Journal of Korea TAPPI, Paper properties improvement by adding microfibrillated cellulose-mineral composites, 48(2); 83-90 (2016)

Lee, J. M., Paper properties improvement by adding microfibrillated cellulose-mineral composites, Journal of Korea TAPPI 48(2):83-90 (2016).

10.7584/ktappi.2016.48.2.083
11
G. B. Nah, S. E. Jung, S. B. Hong, K. J. Kim, J. M. Lee and T. J. Eom, Chemical dispersion of lignocellulosic materials (LCM) by glycol etherProceeding of Spring Conference of the Korea TAPPI; 87 (2017)

Nah, G. B., Jung, S. E., Hong, S. B., Kim, K. J., Lee, J. M., and Eom, T. J., Chemical dispersion of lignocellulosic materials (LCM) by glycol ether, Proceeding of Spring Conference of the Korea TAPPI, p. 87 (2017).

12
E. B. Ahn, S. B. Hong, K. J. Kim and T. J. Eom, Journal of Korea TAPPI, Micro-fibrillated cellulose preparation with enzyme beating pretreatment and effect on paper strength improvement, 47(6); 57-65 (2015)

Ahn, E. B., Hong, S. B., Kim, K. J., and Eom, T. J., Micro-fibrillated cellulose preparation with enzyme beating pretreatment and effect on paper strength improvement, Journal of Korea TAPPI 47(6):57-65 (2015).

10.7584/ktappi.2015.47.6.057
13
K. Syverud, G. Chinga-Carrasco, J. Toledo and P. G. Toledo, Carbohydrate Polymers, A comparative study of Eucalyptus and Pinus radiata pulp fibres as raw materials for production of cellulose nanofibrils, 84(3); 1033-1038 (2011)

Syverud, K., Chinga-Carrasco, G., Toledo, J., and Toledo, P. G., A comparative study of Eucalyptus and Pinus radiata pulp fibres as raw materials for production of cellulose nanofibrils, Carbohydrate Polymers 84(3): 1033-1038 (2011).

10.1016/j.carbpol.2010.12.066
14
J. S. Stevanic and L. Salmén, Cellulose, Characterizing wood polymers in the primary cell wall of Norway spruce (Picea abies (L.) Karst.) using dynamic FT-IR spectroscopy, 15(2); 285-295 (2008)

Stevanic, J. S. and Salmén, L., Characterizing wood polymers in the primary cell wall of Norway spruce (Picea abies (L.) Karst.) using dynamic FT-IR spectroscopy, Cellulose 15(2): 285-295 (2008).

10.1007/s10570-007-9169-1
15
J. M. Lawther, R. Sun and W. B. Banks, Journal of Agricultural and Food Chemistry, Fractional characterization of wheat straw lignin components by alkaline nitrobenzene oxidation and FT-IR spectroscopy, 44(5); 1241-1247 (1996)

Lawther, J. M., Sun, R., and Banks, W. B., Fractional characterization of wheat straw lignin components by alkaline nitrobenzene oxidation and FT-IR spectroscopy, Journal of Agricultural and Food Chemistry 44(5):1241- 1247 (1996).

10.1021/jf9502764
16
X. Colom, F. Carrillo, F. Nogués and P. Garriga, Polymer Degradation and Stability, Structural analysis of photodegraded wood by means of FTIR spectroscopy, 80(3); 534-549 (2003)

Colom, X., Carrillo, F., Nogués, F., and Garriga, P., Structural analysis of photodegraded wood by means of FTIR spectroscopy, Polymer Degradation and Stability 80(3):534-549 (2003).

10.1016/s0141-3910(03)00051-x
17
Y. Huang, L. Wang, Y. Chao, D. S. Nawawi, T. Akiyama, T. Yokoyama and Y. Matsumoto, Journal of Wood Chemistry and Technology, Analysis of lignin aromatic structure in wood based on the IR spectrum, 32(4); 294-303 (2012)

Huang, Y., Wang, L., Chao, Y., Nawawi, D. S., Akiyama, T., Yokoyama, T., and Matsumoto, Y., Analysis of lignin aromatic structure in wood based on the IR spectrum, Journal of Wood Chemistry and Technology 32(4):294- 303 (2012).

10.1080/02773813.2012.666316
18
S. Yoo and J. S. Hsieh, Industrial & Engineering Chemistry Research, Enzyme-assisted preparation of fibrillated cellulose fibers and its effect on physical and mechanical properties of paper sheet composites, 49(5); 2161-2168 (2010)

Yoo, S., and Hsieh, J. S., Enzyme-assisted preparation of fibrillated cellulose fibers and its effect on physical and mechanical properties of paper sheet composites, Industrial & Engineering Chemistry Research 49(5):2161- 2168 (2010).

10.1021/ie901621n
Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 49
  • No :3
  • Pages :109-117
  • Received Date : 2017-06-16
  • Revised Date : 2017-06-21
  • Accepted Date : 2017-06-23
  • DOI :https://doi.org/10.7584/JKTAPPI.2017.06.49.3.109
Journal Informaiton Journal of Korea TAPPI Journal of Korea TAPPI
Online Submission
  • scopus
  • NRF
  • KOFST
  • crossref crossmark
  • crossref cited-by
  • crosscheck
  • orcid
Journal Informaiton Journal Informaiton - close