Thermochemical Properties of Lignin-Silica Hybrid Materials Originated from Rice Husk According to Manufacturing Conditions

Dong Seop Kim; Yong Joo Sung

doi:10.7584/JKTAPPI.2019.12.51.6.52

All Issue

2019 Vol.51, Issue 6 Preview Page Next Page

Thermochemical Properties of Lignin-Silica Hybrid Materials Originated from Rice Husk According to Manufacturing Conditions 제조조건에 따른 왕겨유래 리그닌 실리카 하이브리드 소재의 열화학적 특성 변화

30 December 2019. pp. 52-58

PDF XML

Abstract

The changes in the thermochemical properties of lignin-silica hybrid materials originated from the alkaline black liquor of rice husk were evaluated depending on the pH conditions for sol-gel reaction. The lower pH condition resulted in the higher yield of the lignin-silica hybrid materials and the lower contents of the silica in the lignin-silica hybrid materials. The Thermogravimetric analysis showed the higher weight loss of the lignin-silica materials prepared at the acidic precipitation conditions. The lignin-silica hybrid materials precipitated at pH 7.5 condition showed the less weight loss at 700-900℃ temperature region and the better thermal stability, which resulted from the higher contents of silica and the higher glass transition temperature than those precipitated at the acidic condition. The composition and the properties of the lignin-silica hybrid materials could be changed by the pH condition of the precipitation of the rice husk alkaline black liquor.

Keywords

Lignin-silica hybrid materials

rice husk

thermal stability

alkaline digestion

black liquor

References

Literature Cited

Kelley. S. S., Rials. T. G., and Glasser. W. G., Relaxation behavior of the amorphous components of wood, Journal of Materials Science 22(2):617-624 (1987).

10.1007/BF01160778

Kubo, S. and Kadla, J. F., Hydrogen bonding in lignin: A Fourier transform infrared model compound study, Biomacromolecules 6(5):2815-2821 (2005).

10.1021/bm050288q

Seo, J. H., Kim, M. K., Jeong, H. M., and Kim, Y. S., Studies on the electrochemical properties of lignin/polyaniline composite, Journal of Korea TAPPI 51(4):5-12 (2019)

10.7584/JKTAPPI.2019.08.51.4.5

Stiubianu, G., Cazacu, M., Cristea, M., and Vlad, A., Polysiloxane-lignin composites, Journal of applied polymer science 113(4):2313-2321 (2009).

10.1002/app.30240

Kim, H. M., Kim, D. S., Sung, Y. J., Park, Y. S., and Seo, Y. K., Study of the precipitation of silica from black liquor of rice husk alkine digestion, Journal of Korea TAPPI 49(4):143-149 (2017).

10.7584/JKTAPPI.2017.08.49.4.143

Wittayakun, J., Khemthong, P., and Prayoonpokarach, S., Synthesis and characterization of zeolite NaY from rice husk silica, Korean Journal of Chemical Engineering 25(4):861-864 (2008).

10.1007/s11814-008-0142-y

Iler, K. R., The Chemistry of Silica: Solubility, Polymerization, Colloid and Surface Properties and Biochemistry of Silica, Wiley, NY, USA (1979).

Uloth, V. C. and Wearing, J. T., Kraft lignin recovery: Acid precipitation versus ultrafiltration. Part II: Technology and economics, Pulp Paper Can. 90(10):34-37 (1989).

Sjöström, E., The origin of charge on cellulosic fibers, Nordic Pulp & Paper Research Journal 4(2):90-93 (1989).

10.3183/npprj-1989-04-02-p090-093

Socrates, G., Infrared and Raman Characteristic Group Frequencies: Tables and Charts, John Wiley & Sons, John Wiley & Sons, Chichester, UK (2004).

Wang, X., Guo, Y., Zhou, J., and Sun, G., Structural changes of poplar wood lignin after supercritical pretreatment using carbon dioxide and ethanol-water as co-solvents, RSC Advances 7(14):8314-8322 (2017).

10.1039/C6RA26122A

Klapiszewski, Ł., Królak, M., and Jesionowski, T., Silica synthesis by the sol-gel method and its use in the preparation of multifunctional biocomposites, Central European Journal of Chemistry 12(2):173-184 (2014).

10.2478/s11532-013-0370-9

Bouajila, J., Dole, P., Joly, C., and Limare, A., Some laws of a lignin plasticization, Journal of Applied Polymer Science, 102(2):1445-1451 (2006).

10.1002/app.24299

Feldman, D. and Banu, D., Contribution to the study of rigid PVC polyblends with different lignins, Journal of Applied Polymer Science 66(9):1731-1744 (1997).

10.1002/(SICI)1097-4628(19971128)66:9<1731::AID-APP11>3.0.CO;2-Y

Cui, C., Sadeghifar, H., Sen, S., and Argyropoulos, D. S., Toward thermoplastic lignin polymers; Part II: Thermal & polymer characteristics of kraft lignin & derivatives, BioResources 8(1):864-886 (2013).

10.15376/biores.8.1.864-886

Kadla, J. F. and Kubo, S., Lignin-based polymer blends: Analysis of intermolecular interactions in lignin-synthetic polymer blends, Composites Part A: Applied Science and Manufacturing 35(3):395-400 (2004).

10.1016/j.compositesa.2003.09.019

El Mansouri, N. E., Yuan, Q., and Huang, F., Characterization of alkaline lignins for use in phenol-formaldehyde and epoxy resins, BioResources 6(3):2647-2662 (2011).

Strzemiecka, B., Klapiszewski, Ł., Jamrozik, A., Szalaty, T., Matykiewicz, D., Sterzyński, T., and Jesionowski, T., Physicochemical characterization of functional lignin-silica hybrid fillers for potential application in abrasive tools, Materials 9(7):517 (2016).

10.3390/ma9070517

Information

Publisher :Korea Technical Association of The Pulp and Paper Industry
Publisher(Ko) :한국펄프종이공학회
Journal Title :Journal of Korea TAPPI
Journal Title(Ko) :펄프종이기술
Volume : 51
No :6
Pages :52-58
Received Date : 2019-11-13
Revised Date : 2019-12-05
Accepted Date : 2019-12-06
DOI :https://doi.org/10.7584/JKTAPPI.2019.12.51.6.52

Journal of Korea TAPPI ISSN:0253-3200(Print) 펄프종이기술

All Issue

Literature Cited