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2020 Vol.52, Issue 6 Preview Page
Preparation of Cellulose Nanocrystal-based Poly (m-aminobenzene sulfonate) Copolymer for Heavy Metal Cr (VI) Adsorption

중금속 Cr (Ⅵ) 흡착용 셀룰로오스 나노크리스탈 기반 Poly (m-aminobenzene sulfonate) 공중합체 제조

Yong Ho Yoo1
,
Jin Ho Bae1
,
Liangliang An1
,
Jiansong Chen1
,
Yong Sik Kim2†
유용호 1
,
배진호 1
,
안량량 1
,
진건송 1
,
김용식 2†
1Dept. of Paper Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon, 24341
2Dept. of Paper Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon, 24341
1강원대학교 산림환경과학대학 제지공학과, 학생
2강원대학교 산림환경과학대학 제지공학과, 교수
†Corresponding author: E-Mail: yongsikk@kangwon.ac.kr (Address: Dept. of Paper Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon, 24341, Republic of Korea)
30 December 2020. pp. 110-122
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Abstract

In this study, we have synthesized cellulose nanocrystal-based poly (m-aminobenzene sulfonate) (PABS) copolymer by copolymerization with a conductive PABS onto cellulose nanocrystal (CNC) as a high value-added biomaterial application and its chemical structure analysis and Cr (VI) adsorption efficiency were analyzed. The chemical structure analysis of PABS and CNC-PABS confirmed that each functional group and bonding structure of them was identified and ultimately, CNC-PABS was successfully prepared. In addition, CNC-PABS was found to adsorb 100% Cr (V) in the 30 mL of Cr (VI) aqueous solution (2.5 mg/L) when 191.6 mg of CNC-PABS added, showing the theoretical maximum adsorption of Cr (VI) by CNC-PABS was found to be 99.81 mg/g. However, the adsorption efficiency was dependent on the pH range. 100% Cr (VI) was adsorbed in the pH range of 1~3, while the adsorption efficiency rapidly decreased as the pH was increased from 3 to 12. This was because the amine of PABS formed quaternary ammonium cation under acidic conditions, adsorbing anion species from Cr (VI) by electrostatic attraction but the adsorption effect was greatly reduced by electrostatic repulsion due to the sulfonate anions of PABS formed under alkaline conditions.

Keywords
Biomaterial
cellulose nanocrystals (CNC)
conductive PABS polymer
Cr (VI) adsorbent
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Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 52
  • No :6
  • Pages :110-122
  • Received Date : 2020-11-30
  • Revised Date : 2020-12-15
  • Accepted Date : 2020-12-17
  • DOI :https://doi.org/10.7584/JKTAPPI.2020.12.52.6.110
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