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2019 Vol.51, Issue 1 Preview Page
Dissolution of Cellulosic Material with Glycol Ether/NaOH Aqueous Solution

Glycol Ether/NaOH 수용액에 의한 셀룰로오스계 시료의 용해

Ji-Ae Ryu
,
Kang-Jae Kim1
,
Eun-Byeol Ahn1
,
Tae-Jin Eom2†
류지애
,
김강재 1
,
안은별 1
,
엄태진 2†
Department of Wood Science and Technology, Kyungpook National University, Daegu, 41566
1Agricultural Science and Technology Research Institute, Kyungpook National University, Daegu, 41566
2Major in Wood Science and Technology, Dept. of Wood Science and Technology, School of Forestry, Science and Landscape Architecture, Kyungpook National University, Daegu, 41566
경북대학교 임산공학과
1경북대학교 농업과학기술연구소
2경북대학교 산림과학·조경학부 임산공학전공
†Corresponding author: E-Mail: tjeom@knu.ac.kr
28 February 2019. pp. 19-27
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Abstract

The dissolution characteristics of glycol ether/NaOH solution were compared with NaOH/urea and PEG/NaOH solutions were reported. With decreasing of the particle size and concentration of the cellulosic micro-fines (CMFs), the dissolution ability of the CMFs was drastically increased in all solvents. Compared with the PEG/NaOH solution, the glycol ether/NaOH solution had been found to exhibit a similar or higher regenerated cellulose degree of polymerization as well as solubility. The FT-IR analysis also identified the differences between natural cellulose and regenerated cellulose. The shortening of particle length in the filter paper non-dissolved part was observed through optical microscopy, and for CMFs, swelling were observed in most particles. These results confirmed that the properties of raw materials particle size and degree of polymerization had a significant effect on dissolution and the glycol ether/NaOH solutions was a new solvent.

Keywords
Dissolution
microwave organosolv
cellulose micro-fines (CMFs)
NaOH aqueous solution
References

Literature Cited

1
Y. Habibi, L. A. Lucia and O. J. Rojas, Chemical reviews, Cellulose nanocrystals: Chemistry, self-assembly, and applications, 110(6); 3479-3500 (2010)

Habibi, Y., Lucia, L. A., and Rojas, O. J., Cellulose nanocrystals: Chemistry, self-assembly, and applications, Chemical reviews 110(6):3479-3500 (2010).

10.1021/cr900339w
2
C. Tsioptsias, A. Stefopoulos, I. Kokkinomalis, L. Papadopoulou and C. Panayiotou, Green Chemistry, Development of micro-and nano-porous composite materials by processing cellulose with ionic liquids and supercritical CO2, 10(9); 965-971 (2008)

Tsioptsias, C., Stefopoulos, A., Kokkinomalis, I., Papadopoulou, L., and Panayiotou, C., Development of micro-and nano-porous composite materials by processing cellulose with ionic liquids and supercritical CO2, Green Chemistry 10(9):965-971 (2008).

10.1039/b803869d
3
K. Hattori, J. A. Cuculo and S. M. Hudson, Journal of Polymer Science Part A: Polymer Chemistry, New solvents for cellulose: Hydrazine/thiocyanate salt system, 40(4); 601-611 (2002)

Hattori, K., Cuculo, J. A., and Hudson, S. M., New solvents for cellulose: Hydrazine/thiocyanate salt system, Journal of Polymer Science Part A: Polymer Chemistry 40(4):601-611 (2002).

10.1002/pola.10135
4
B. A. Ass, M. N. Belgacem and E. Frollini, N-dimethylacetamide/lithium chloride, Carbohydrate Polymers, Mercerized linters cellulose: Characterization and acetylation in N, 63(1); 19-29 (2006)

Ass, B. A., Belgacem, M. N., and Frollini, E., Mercerized linters cellulose: Characterization and acetylation in N, N-dimethylacetamide/lithium chloride, Carbohydrate Polymers 63(1):19-29 (2006).

10.1016/j.carbpol.2005.06.010
5
J. Trygg and P. Fardim, Cellulose, Enhancement of cellulose dissolution in water-based solvent via ethanol-hydrochloric acid pretreatment, 18(4); 987-994 (2011)

Trygg, J. and Fardim, P., Enhancement of cellulose dissolution in water-based solvent via ethanol-hydrochloric acid pretreatment, Cellulose 18(4):987-994 (2011).

10.1007/s10570-011-9550-y
6
D. Gagnaire, D. Mancier and M. Vincendon, Journal of Polymer Science: Polymer Chemistry Edition, Cellulose organic solutions: A nuclear magnetic resonance investigation, 18(1); 13-25 (1980)

Gagnaire, D., Mancier, D., and Vincendon, M., Cellulose organic solutions: A nuclear magnetic resonance investigation, Journal of Polymer Science: Polymer Chemistry Edition 18(1):13-25 (1980).

10.1002/pol.1980.170180102
7
H. Dogan and N. D. Hilmioglu, Carbohydrate Polymers, Dissolution of cellulose with NMMO by microwave heating, 75(1); 90-94 (2009)

Dogan, H. and Hilmioglu, N. D., Dissolution of cellulose with NMMO by microwave heating, Carbohydrate Polymers 75(1):90-94 (2009).

10.1016/j.carbpol.2008.06.014
8
T. Rosenau, A. Potthast, H. Sixta and P. Kosma, Progress in Polymer Science, The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process), 26(9); 1763-1837 (2001)

Rosenau, T., Potthast, A., Sixta, H., and Kosma, P., The chemistry of side reactions and byproduct formation in the system NMMO/cellulose (Lyocell process), Progress in Polymer Science 26(9):1763-1837 (2001).

10.1016/S0079-6700(01)00023-5
9
H. Wang, G. Gurau and R. D. Rogers, Chemical Society Reviews, Ionic liquid processing of cellulose, 41(4); 1519-1537 (2012)

Wang, H., Gurau, G., and Rogers, R. D., Ionic liquid processing of cellulose, Chemical Society Reviews 41(4):1519-1537 (2012).

10.1039/c2cs15311d
10
S. Dorn, F. Wendler, F. Meister and T. Heinze, Macromolecular Materials and Engineering, Interactions of ionic liquids with polysaccharides-7: Thermal stability of cellulose in ionic liquids and N-methylmorpholine-N-oxide, 293(11); 907-913 (2008)

Dorn, S., Wendler, F., Meister, F., and Heinze, T., Interactions of ionic liquids with polysaccharides-7: Thermal stability of cellulose in ionic liquids and N-methylmorpholine-N-oxide, Macromolecular Materials and Engineering 293(11):907-913 (2008).

10.1002/mame.200800153
11
F. Wendler, L. N. Todi and F. Meister, Thermochimica Acta, Thermostability of imidazolium ionic liquids as direct solvents for cellulose, 528; 76-84 (2012)

Wendler, F., Todi, L. N., and Meister, F., Thermostability of imidazolium ionic liquids as direct solvents for cellulose, Thermochimica Acta 528:76-84 (2012).

10.1016/j.tca.2011.11.015
12
S. Wang, A. Lu and L. Zhang, Progress in Polymer Science, Recent advances in regenerated cellulose materials, 53; 169-206 (2016)

Wang, S., Lu, A., and Zhang, L., Recent advances in regenerated cellulose materials, Progress in Polymer Science 53:169-206 (2016).

10.1016/j.progpolymsci.2015.07.003
13
J. Cai and L. Zhang, Macromolecular Bioscience, Rapid dissolution of cellulose in LiOH/urea and NaOH/urea aqueous solutions, 5(6); 539-548 (2005)

Cai, J. and Zhang, L., Rapid dissolution of cellulose in LiOH/urea and NaOH/urea aqueous solutions, Macromolecular Bioscience 5(6):539-548 (2005).

10.1002/mabi.200400222
14
J. Cai and L. Zhang, Biomacromolecules, Unique gelation behavior of cellulose in NaOH/urea aqueous solution, 7(1); 183-189 (2006)

Cai, J. and Zhang, L., Unique gelation behavior of cellulose in NaOH/urea aqueous solution, Biomacromolecules 7(1):183-189 (2006).

10.1021/bm0505585
15
J. Chen, S. K. Spear, J. G. Huddleston and R. D. Rogers, Green Chemistry, Polyethylene glycol and solutions of polyethylene glycol as green reaction media, 7(2); 64-82 (2005)

Chen, J., Spear, S. K., Huddleston, J. G., and Rogers, R. D., Polyethylene glycol and solutions of polyethylene glycol as green reaction media, Green Chemistry 7(2):64-82 (2005).

10.1039/b413546f
16
L. Yan and Z. Gao, Cellulose, Dissolving of cellulose in PEG/NaOH aqueous solution, 15(6); 789-796 (2008)

Yan, L. and Gao, Z., Dissolving of cellulose in PEG/NaOH aqueous solution, Cellulose 15(6):789-796 (2008).

10.1007/s10570-008-9233-5
17
K. Kamida, K. Okajima, T. Matsui and K. Kowsaka, Polymer Journal, Study on the solubility of cellulose in aqueous alkali solution by deuteration IR and 13C NMR, 16(12); 857-866 (1984)

Kamida, K., Okajima, K., Matsui, T., and Kowsaka, K., Study on the solubility of cellulose in aqueous alkali solution by deuteration IR and 13C NMR, Polymer Journal 16(12):857-866 (1984).

10.1295/polymj.16.857
18
G. B. Nah, J. A. Ryu, J. M. Lee and T. J. Eom, Journal of Korea TAPPI, Chemical micronization of woody biomass using the microwave, 49(4); 150-158 (2017)

Nah, G. B., Ryu, J. A., Lee, J. M., and Eom, T. J., Chemical micronization of woody biomass using the microwave, Journal of Korea TAPPI 49(4):150-158 (2017).

10.7584/jktappi.2017.08.49.4.150
19
Z. Shi, Q. Yang, S. Kuga and Y. Matsumoto, Journal of Agricultural and Food Chemistry, Dissolution of wood pulp in aqueous NaOH/Urea solution via dilute acid pretreatment, 63(27); 6113-6119 (2015)

Shi, Z., Yang, Q., Kuga, S., and Matsumoto, Y., Dissolution of wood pulp in aqueous NaOH/Urea solution via dilute acid pretreatment, Journal of Agricultural and Food Chemistry 63(27):6113-6119 (2015).

10.1021/acs.jafc.5b01714
20
R. Shinoda, T. Saito, Y. Okita and A. Isogai, Biomacromolecules, Relationship between length and degree of polymerization of TEMPO-oxidized cellulose nanofibrils, 13(3); 842-849 (2012)

Shinoda, R., Saito, T., Okita, Y., and Isogai, A., Relationship between length and degree of polymerization of TEMPO-oxidized cellulose nanofibrils, Biomacromolecules 13(3):842-849 (2012).

10.1021/bm2017542
21
L. E. I. F. Jörgensen, Acta Chemica Scandinavica, Swelling and heterogeneous hydrolysis of cotton linters and wood pulp fibers related to their fine structure, 4; 185-199 (1950)

Jörgensen, L. E. I. F., Swelling and heterogeneous hydrolysis of cotton linters and wood pulp fibers related to their fine structure, Acta Chemica Scandinavica 4:185-199 (1950).

10.3891/acta.chem.scand.04-0185
22
P. Gonzalez-Tello, F. Camacho and G. Blazquez, Journal of Chemical and Engineering Data, Density and viscosity of concentrated aqueous solutions of polyethylene glycol, 39(3); 611-614 (1994)

Gonzalez-Tello, P., Camacho, F., and Blazquez, G., Density and viscosity of concentrated aqueous solutions of polyethylene glycol, Journal of Chemical and Engineering Data 39(3):611-614 (1994).

10.1021/je00015a050
23
S. Karaman, A. Karaipekli, A. Sarı and A. Bicer, Solar Energy Materials and Solar Cells, Polyethylene glycol (PEG)/diatomite composite as a novel form-stable phase change material for thermal energy storage, 95(7); 1647-1653 (2011)

Karaman, S., Karaipekli, A., Sarı, A., and Bicer, A., Polyethylene glycol (PEG)/diatomite composite as a novel form-stable phase change material for thermal energy storage, Solar Energy Materials and Solar Cells 95(7):1647-1653 (2011).

10.1016/j.solmat.2011.01.022
24
X. Hu, Y. Du, Y. Tang, Q. Wang, T. Feng, J. Yang and J. F. Kennedy, Carbohydrate Polymers, Solubility and property of chitin in NaOH/urea aqueous solution, 70(4); 451-458 (2007)

Hu, X., Du, Y., Tang, Y., Wang, Q., Feng, T., Yang, J., and Kennedy, J. F., Solubility and property of chitin in NaOH/urea aqueous solution, Carbohydrate Polymers 70(4):451-458 (2007).

10.1016/j.carbpol.2007.05.002
25
A. Isogai and R. H. Atalla, Cellulose, Dissolution of cellulose in aqueous NaOH solutions, 5(4); 309-319 (1998)

Isogai, A. and Atalla, R. H., Dissolution of cellulose in aqueous NaOH solutions, Cellulose 5(4):309-319 (1998).

10.1023/A:1009272632367
26
Z. D. Ding, Z. Chi, W. X. Gu, S. M. Gu, J. H. Liu and H. J. Wang, Carbohydrate Polymers, Theoretical and experimental investigation on dissolution and regeneration of cellulose in ionic liquid, 89(1); 7-16 (2012)

Ding, Z. D., Chi, Z., Gu, W. X., Gu, S. M., Liu, J. H., and Wang, H. J., Theoretical and experimental investigation on dissolution and regeneration of cellulose in ionic liquid, Carbohydrate Polymers 89(1):7-16 (2012).

10.1016/j.carbpol.2012.01.080
27
R. C. Sun, J. M. Fang, J. Tomkinson, Z. C. Geng and J. C. Liu, Carbohydrate Polymers, Fractional isolation, physico-chemical characterization and homogeneous esterification of hemicelluloses from fast-growing poplar wood, 44(1); 29-39 (2001)

Sun, R. C., Fang, J. M., Tomkinson, J., Geng, Z. C., and Liu, J. C., Fractional isolation, physico-chemical characterization and homogeneous esterification of hemicelluloses from fast-growing poplar wood, Carbohydrate Polymers 44(1):29-39 (2001).

10.1016/S0144-8617(00)00196-X
Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 51
  • No :1
  • Pages :19-27
  • Received Date : 2019-01-22
  • Revised Date : 2019-02-13
  • Accepted Date : 2019-02-15
  • DOI :https://doi.org/10.7584/JKTAPPI.2019.02.51.1.19
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