Sulfonation of HwBKP by Sulfur Trioxide Pyridine Complex and Preparation of Anionic Cellulose Beads Using the Same

Younglae Kim; Dohyeon Heo; Byoung-Uk Cho

doi:10.7584/JKTAPPI.2023.4.55.2.10

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2023 Vol.55, Issue 2 Preview Page Next Page

Research Article

Sulfonation of HwBKP by Sulfur Trioxide Pyridine Complex and Preparation of Anionic Cellulose Beads Using the Same Sulfur Trioxide Pyridine Complex를 이용한 HwBKP의 설폰화 및 이를 이용한 음이온성 셀룰로오스 비즈 제조

30 April 2023. pp. 10-18

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Abstract

To expand the applications of cellulose beads, sulfonated cellulose beads were prepared by chemically modifying HwBKP fibers with sulfur trioxide pyridine complex (STP), dissolving in tetraethylammonium hydroxide (TEAOH)/urea solvent, and dropping into acetic acid solution. The effect of the amount of STP added on the properties of sulfonated cellulose solution and cellulose beads was investigated. It was observed that the sulfonated cellulose beads exhibited anionic surface charge in a fairly wide pH range, and the degree of substitution of sulfonic acid groups and the zeta potential of the cellulose beads could be controlled by adjusting the amount of added STP. In addition, as the amount of STP added increased, the crystallinity of the cellulose decreased, the viscosity and surface tension of the sulfonated cellulose/TEAOH/urea solution decreased, and the size of the cellulose beads increased.

Keywords

Anionic cellulose beads

chemical modification

sulfur trioxide pyridine complex

surface tension

zeta potential

crystallinity

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Information

Publisher :Korea Technical Association of The Pulp and Paper Industry
Publisher(Ko) :한국펄프종이공학회
Journal Title :Journal of Korea TAPPI
Journal Title(Ko) :펄프종이기술
Volume : 55
No :2
Pages :10-18
Received Date : 2023-02-16
Revised Date : 2023-04-10
Accepted Date : 2023-04-11
DOI :https://doi.org/10.7584/JKTAPPI.2023.4.55.2.10

Journal of Korea TAPPI ISSN:0253-3200(Print) 펄프종이기술

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