Effect of the Wet-end Addition of Cationic Cellulose Nanofibril on Paper Strength

Kyung Min Kim; Ji Young Lee; Chul Hwan Kim; Tae Ung Park; Hae Min Jo

doi:10.7584/JKTAPPI.2018.04.50.2.29

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Effect of the Wet-end Addition of Cationic Cellulose Nanofibril on Paper Strength 양이온성 셀룰로오스 나노피브릴의 내첨적용에 따른 종이의 강도 변화 평가

30 April 2018. pp. 29-35

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Abstract

Because cellulose nanofibrils (CNF) made from bleached kraft pulp are small and contain anionic carboxylic acids, papermakers can not expect a high retention of CNFs in the papermaking process. If the CNFs are cationic, they can be retained on the anionic cellulosic fibers and improve the paper strength. In this study, we manufactured cationic CNFs by quaterizing the CNFs made from bleached hardwood kraft pulp (HwBKP). After the cationic CNFs were prepared, their particle size, zeta-potential, and fiber width were measured. Handsheets were made by adding cationic CNFs to the stock containing softwood bleached kraft pulp (SwBKP) and HwBKP, and the strengths of the handsheets were analyzed. The zeta-potential value of the CNFs changed from negative to positive after quaterization, but the particle size and fiber width of the CNFs did not change significantly. The CNFs improved the strength of the handsheets, linearly, and the paper strength was greater in the cationic CNF than the untreated CNF. It was concluded that cationic CNF was more effective at improving the paper strength by increasing the fiber bonds than the untreated and negative CNF.

Keywords

Cellulose nanofibril

quaternization

cationic

negative

paper strength

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Information

Publisher :Korea Technical Association of The Pulp and Paper Industry
Publisher(Ko) :한국펄프종이공학회
Journal Title :Journal of Korea TAPPI
Journal Title(Ko) :펄프종이기술
Volume : 50
No :2
Pages :29-35
Received Date : 2018-04-10
Revised Date : 2018-04-20
Accepted Date : 2018-04-23
DOI :https://doi.org/10.7584/JKTAPPI.2018.04.50.2.29

Journal of Korea TAPPI ISSN:0253-3200(Print) 펄프종이기술

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Literature Cited