Effect of Surface-Modified Cellulose Nanofibril with Cationic Polyelectrolyte on Drainage and Strength of Paper

Kyung Min Kim; Ji Young Lee; Hae Min Jo; Su Ho Kim; Chul Hwan Kim

doi:10.7584/JKTAPPI.2019.08.51.4.29

All Issue

2019 Vol.51, Issue 4 Preview Page Next Page

Effect of Surface-Modified Cellulose Nanofibril with Cationic Polyelectrolyte on Drainage and Strength of Paper 양이온성 고분자전해질로 표면개질된 셀룰로오스 나노피브릴의 내첨처리에 따른 종이의 강도 및 탈수성 분석

30 August 2019. pp. 29-35

PDF XML

Abstract

In this study, we evaluated the effect of the surface-modified cellulose nanofibril (CNF) on the strength, drainage, and retention of the specialty paper made from cotton lint mixed pulp (CLMP). The surface modification of CNF was conducted via enzymatic hydrolysis and homogenization using cationic polyacrylamide (C-PAM) to yield enzyme (EN)-CNF. C-PAM was added into a 0.5% CNF slurry for 5 min at 600 rpm. After performing surface modification, the viscosity, particle size, and fiber width of the unmodified and surface-modified CNFs were measured. Further, handsheets were produced by adding CNF or EN-CNF into the CLMP furnish. The drainage rate and chemical oxygen demand of the CLMP furnish were determined to evaluate the effect of surface modification on the drainability and retention in the wet-end part. There were no significant differences in terms of the viscosity, particle size, and fiber width when comparing unmodified and surface-modified CNFs. The surface-modified CNF handsheets exhibited higher tensile strength and folding endurance when compared with those exhibited by the unmodified CNF handsheets. Additionally, surface modification increased the drainage rate and decreased the COD of the CLMP furnish. Therefore, the surface modification of CNF positively affected the specialty paper in terms of strength, drainage, and retention.

Keywords

Enzyme cellulose nanofibril

polyelectrolyte

cationized cellulose nanofibril

surface modification

drainage rate

physical properties

References

Literature Cited

H. P. S. Abdul Khalil, A. H. Bhat and I. Yusra, Carbohydrate Polymers, Green composites from sustainable cellulose nanofibrils: A review, 87(2); 963-979 (2012)

Abdul Khalil, H. P. S., Bhat, A. H., and Yusra, I., Green composites from sustainable cellulose nanofibrils: A review, Carbohydrate Polymers 87(2):963-979 (2012).

10.1016/j.carbpol.2011.08.078

I. Siro and D. Plackett, Cellulose, Microfibrillated cellulose and new nanocomposite materials: A review, 17(3); 459-494 (2010)

Siro, I. and Plackett, D., Microfibrillated cellulose and new nanocomposite materials: A review, Cellulose 17(3):459-494 (2010).

O. Nechyporchuk, M. N. Belgacem and J. Bras, Industrial Crops and Products, Production of cellulose nanofibrils: A review of recent advances, 93; 2-25 (2016)

Nechyporchuk, O., Belgacem, M. N., and Bras, J., Production of cellulose nanofibrils: A review of recent advances, Industrial Crops and Products 93:2-25 (2016).

10.1016/j.indcrop.2016.02.016

N. Lavoine, I. Desloges, A. Dufresne and J. Bras, Carbohydrate Polymers, Microfibrillated cellulose - Its barrier properties and application in cellulosic materials: A review, 90(2); 735-764 (2012)

Lavoine, N., Desloges, I., Dufresne, A., and Bras, J., Microfibrillated cellulose - Its barrier properties and application in cellulosic materials: A review, Carbohydrate Polymers 90(2):735-764 (2012).

10.1016/j.carbpol.2012.05.026

J. F. Bobalek, (Second Edition). Paper products: Security applications, In Encyclopedia of Materials: Science and Technology; 6704-6706, Oxford, UK. Pergamon. (2001)

Bobalek, J. F., Paper products: Security applications, In Encyclopedia of Materials: Science and Technology (Second Edition), pp. 6704-6706, Pergamon, Oxford, UK (2001).

J. Rantanen and T. C. Maloney, Nordic Pulp & Paper Research Journal, Press dewatering and nip rewetting of paper containing nano- and microfibril cellulose, 28(4); 582-587 (2013)

Rantanen, J. and Maloney, T. C., Press dewatering and nip rewetting of paper containing nano- and microfibril cellulose, Nordic Pulp & Paper Research Journal 28(4):582-587 (2013).

10.3183/npprj-2013-28-04-p582-587

T. Tero, O. Monika, N. Antti, R. Janne and L. Janne, Cellulose, Effect of microfibrillated cellulose and fines on the drainage of kraft pulp suspension and paper strength, 17(5); 1005-1020 (2010)

Tero, T., Monika, O., Antti, N., Janne, R., and Janne, L., Effect of microfibrillated cellulose and fines on the drainage of kraft pulp suspension and paper strength, Cellulose 17(5):1005-1020 (2010).

F. Rol, M. N. Belgacem, A. Gandini and J. Bras, Progress in Polymer Science, Recent advances in surface-modified cellulose nanofibrils, 88; 241-264 (2019)

Rol, F., Belgacem, M. N., Gandini, A., and Bras, J., Recent advances in surface-modified cellulose nanofibrils, Progress in Polymer Science 88:241–264 (2019).

10.1016/j.progpolymsci.2018.09.002

S. Kalia, S. Boufi, A. Celli and S. Kango, Colloid and Polymer Science, Nanofibrillated cellulose: Surface modification and potential applications, 292(1); 5-31 (2014)

Kalia, S., Boufi, S., Celli, A., and Kango, S., Nanofibrillated cellulose: Surface modification and potential applications, Colloid and Polymer Science 292(1):5-31 (2014).

10.1007/s00396-013-3112-9

W. K. J. Mosse, D. V. Boger, G. P. Simon and G. Garnier, American Chemical Society, Effect of cationic polyacrylamides on the interactions between cellulose fibers, 28(7); 3641-3649 (2012)

Mosse, W. K. J., Boger, D. V., Simon, G. P., and Garnier, G., Effect of cationic polyacrylamides on the interactions between cellulose fibers, American Chemical Society 28(7):3641-3649 (2012).

10.1021/la2049579

F. L. Hatton, E. Malmstrom and A. Carlmark, European Polymer Journal, Tailor-made copolymers for the adsorption to cellulosic surfaces, 65; 325-339 (2015)

Hatton, F. L., Malmstrom, E., and Carlmark, A., Tailor-made copolymers for the adsorption to cellulosic surfaces, European Polymer Journal 65:325-339 (2015).

10.1016/j.eurpolymj.2015.01.026

S. Boufi, I. González, M. Delgado-Aguilar, Q. Tarrès, M. À. Pèlach and P. Mutjé, Carbohydrate Polymers, Nanofibrillated cellulose as an additive in papermaking process: A review, 154; 151-166 (2016)

Boufi, S., González, I., Delgado-Aguilar, M., Tarrès, Q., Pèlach, M. À., and Mutjé, P., Nanofibrillated cellulose as an additive in papermaking process: A review, Carbohydrate Polymers 154:151-166 (2016).

10.1016/j.carbpol.2016.07.117

J. Y. Lee, T. U. Park, E. H. Kim, H. M. Jo, C. H. Kim, T. Y. Kim, Y. D. Heo, J. H. Lee and J. K. Kim, Journal of Korea TAPPI, Study on surface modification of cellulose nanofibril with cationic polyelectrolyte, 50(4); 116-122 (2018)

Lee, J. Y., Park, T. U., Kim, E. H., Jo, H. M., Kim, C. H., Kim, T. Y., Heo, Y. D., Lee, J. H., and Kim, J. K., Study on surface modification of cellulose nanofibril with cationic polyelectrolyte, Journal of Korea TAPPI 50(4):116-122 (2018).

10.7584/jktappi.2018.08.50.4.116

Information

Publisher :Korea Technical Association of The Pulp and Paper Industry
Publisher(Ko) :한국펄프종이공학회
Journal Title :Journal of Korea TAPPI
Journal Title(Ko) :펄프종이기술
Volume : 51
No :4
Pages :29-35
Received Date : 2019-07-05
Revised Date : 2019-07-22
Accepted Date : 2019-07-24
DOI :https://doi.org/10.7584/JKTAPPI.2019.08.51.4.29

Journal of Korea TAPPI ISSN:0253-3200(Print) 펄프종이기술

All Issue

Literature Cited