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2019 Vol.51, Issue 4
Studies on the Electrochemical Properties of Lignin/Polyaniline Composite

리그닌/폴리아닐린 복합체의 전기화학적 특성 연구

Jin Ho Seo1
,
Mun Kyoung Kim2
,
Hyung Mo Jeong2†
,
Yong Sik Kim13‡
서진호 1
,
김문경 2
,
정형모 2†
,
김용식 13‡
1Institute of Forest Science, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon, 24341
2Division. of Mechanical & Biomedical, Mechatronics, and Materials Science and Engineering, College of Engineering, Kangwon National University, Chuncheon, 24341
3Division of Forest Material Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon, 24341
1강원대학교 산림과학연구소
2강원대학교 공과대학 기계의용·메카트로닉스·재료공학부
3강원대학교 산림환경과학대학 산림응용공학부
†Corresponding author: E-Mail: hmjeong704@kangwon.ac.kr
‡Co-corresponding Author: E-Mail: yongsikk@kangwon.ac.kr
30 August 2019. pp. 5-12
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Abstract

In this study, we have synthesized a lignin/polyaniline composite using a typical conductive polymer as a high value-added biomaterial. Further, the morphological characteristics as well as the chemical and electrochemical properties of the lignin/polyaniline composite were evaluated. The morphological analysis of the composite denoted that polyaniline particles, smaller than the lignin particles, formed near the surface of the lignin particles. In addition, FT-IR (Fourier-transform infrared spectroscopy) analysis of the composite revealed that the intrinsic peaks corresponding to lignin considerably reduced or even disappeared and that the lignin/polyaniline interaction occurred because of the shifting of the main polyaniline peaks. Although the electrochemical properties of lignin were considerably poor, the composite exhibited good characteristics. In particular, the capacitance of lignin, lignin/polyaniline composite, and pure polyaniline were 1.52, 131.75, and 214.44 mF·cm-2, i.e., the capacitance of the composite was lower than that of pure polyaniline but considerably higher than that of lignin. Because the lignin content in the composite was approximately 55%, the resulting capacitance was considered to be good.

Keywords
Lignin
polyaniline
composite
electrochemical properties
References

Literature Cited

1
Orbisresearch, Global lignin products market - segmented by product type, source, application, and geography - trends and forecasts 2017 – 2022, https://www.researchandmarkets.com/reports/4390046/global-lignin-products-market-segmented-by (2017)

Orbisresearch, 2017. Global lignin products market - segmented by product type, source, application, and geography - trends and forecasts 2017 – 2022. https://www.researchandmarkets.com/reports/4390046/global-lignin-products-market-segmented-by

2
J. H. Seo, J. H. Bae, C. S. Choi, H. W. Lee, H. Jeong and Y. S. Kim, Journal of Korea TAPPI, Studies on the physical and chemical properties of lignins extracted from various pretreatment methods, 50(5); 76-85 (2018)

Seo, J. H., Bae, J. H., Choi, C. S., Lee, H. W., Jeong, H., and Kim, Y. S., Studies on the physical and chemical properties of lignins extracted from various pretreatment methods, Journal of Korea TAPPI 50(5):76-85 (2018).

10.7584/jktappi.2018.10.50.5.76
3
S. P. Moon, Utilization of lignin: Past, present, futureProceeding of Fall Conference of KTAPPI, Chuncheon, Korea; 34 (2013)

Moon, S. P., Utilization of lignin: Past, present, future, Proceeding of Fall Conference of KTAPPI, Chuncheon, Korea, p.34 (2013).

4
Y. Qin, D. Yang, W. Guo and X. Qiu, Journal of Industrial and Engineering Chemistry, Investigation of grafted sulfonated alkali lignin polymer as dispersant in coal-water slurry, 27; 192-200 (2015)

Qin, Y., Yang, D., Guo, W., and Qiu, X., Investigation of grafted sulfonated alkali lignin polymer as dispersant in coal-water slurry, Journal of Industrial and Engineering Chemistry 27:192-200 (2015).

10.1016/j.jiec.2014.12.034
5
L. Ferry, G. Dorez, A. Taguet, B. Otazaghine and J. M. Lopez-Cuesta, Polymer Degradation and Stability, Chemical modification of lignin by phosphorus molecules to improve the fire behavior of polybutylene succinate, 113; 135-143 (2015)

Ferry, L., Dorez, G., Taguet, A., Otazaghine, B., and Lopez-Cuesta, J. M., Chemical modification of lignin by phosphorus molecules to improve the fire behavior of polybutylene succinate, Polymer Degradation and Stability 113:135-143 (2015).

10.1016/j.polymdegradstab.2014.12.015
6
R. L. Shogren and A. Biswas, Carbohydrate Polymers, Preparation of starch-sodium lignosulfonate graft copolymers via laccase catalysis and characterization of antioxidant activity, 91(2); 581-585 (2013)

Shogren, R. L. and Biswas, A., Preparation of starch-sodium lignosulfonate graft copolymers via laccase catalysis and characterization of antioxidant activity, Carbohydrate Polymers 91(2):581-585 (2013).

10.1016/j.carbpol.2012.08.079
7
R. Kikuchi and H. Goto, Futurum-Tsukuba Science Journal, Polyaniline/lignin composite prepared by oxidative polymerization, 1; 16-18 (2017)

Kikuchi, R. and Goto, H., Polyaniline/lignin composite prepared by oxidative polymerization, Futurum-Tsukuba Science Journal 1:16-18 (2017).

8
H. I. Seo, S. K. Kim, W. J. Youe and Y. S. Kim, Journal of Korea TAPPI, Fabrication and electrochemical characteristic analysis of iodine-doped kraft lignin/polypyrrole conductive fiber mats, 50(5); 37-47 (2018)

Seo, H. I., Kim, S. K., Youe, W. J., and Kim, Y. S., Fabrication and electrochemical characteristic analysis of iodine-doped kraft lignin/polypyrrole conductive fiber mats, Journal of Korea TAPPI 50(5):37-47 (2018).

10.7584/jktappi.2018.10.50.5.39
9
J. H. Park, S. H. Lee, J. Y. Kim and Y. I. Joe, Korean Chemical Engineering Research, The electrochemical characteristics and secondary doping effects of poly[sodium 4-styrenesulfonate] doped polyaniline, 40(6); 729-734 (2002)

Park, J. H., Lee, S. H., Kim, J. Y., and Joe, Y. I., The electrochemical characteristics and secondary doping effects of poly[sodium 4-styrenesulfonate] doped polyaniline, Korean Chemical Engineering Research 40(6):729-734 (2002).

10
E. S. Matveeva and M. J. Gonzalez-Tejera, Journal of the Electrochemical Society, Impedance study of the charge-transfer interaction between the polyaniline chain and redox pair in solution, 147(3); 1213-1221 (2000)

Matveeva, E. S. and Gonzalez-Tejera, M. J., Impedance study of the charge-transfer interaction between the polyaniline chain and redox pair in solution, Journal of the Electrochemical Society 147(3):1213-1221 (2000).

10.1149/1.1393339
11
J. I. Kroschwitz, Electrical and Electronic Properties of Polymers: A State-of-the-Art Compendium, New York. Wiley-Interscience. (1988)

Kroschwitz, J. I., Electrical and Electronic Properties of Polymers: A State-of-the-Art Compendium, Wiley-Interscience, New York (1988).

12
A. G. Yavuz, E. Dincturk-Atalay, A. Uygun, F. Gode and E. Aslan, Desalination, A comparison study of adsorption of Cr(VI) from aqueous solutions onto alkyl-substituted polyaniline/chitosan composites, 279(1-3); 325-331 (2011)

Yavuz, A. G., Dincturk-Atalay, E., Uygun, A., Gode, F., and Aslan, E., A comparison study of adsorption of Cr(VI) from aqueous solutions onto alkyl-substituted polyaniline/chitosan composites, Desalination 279(1-3):325-331 (2011).

10.1016/j.desal.2011.06.034
13
M. Bhaumik, A. Maity, V. V. Srinivasu and M. S. Onyango, Chemical Engineering Journal, Removal of hexavalent chromium from aqueous solution using polypyrrole-polyaniline nanofibers, 181; 323-333 (2012)

Bhaumik, M., Maity, A., Srinivasu, V. V., and Onyango, M. S., Removal of hexavalent chromium from aqueous solution using polypyrrole-polyaniline nanofibers, Chemical Engineering Journal 181:323-333 (2012).

14
P. C. Rodrigues, M. P. Cantão, P. Janissek, P. C. Scarpa, A. L. Mathias, L. P. Ramos and M. A. Gomes, European Polymer Journal, Polyaniline/lignin blends: FTIR, MEV and electrochemical characterization, 38(11); 2213-2217 (2002)

Rodrigues, P. C., Cantão, M. P., Janissek, P., Scarpa, P. C., Mathias, A. L., Ramos, L. P., and Gomes, M. A., Polyaniline/lignin blends: FTIR, MEV and electrochemical characterization, European Polymer Journal 38(11):2213-2217 (2002).

10.1016/s0014-3057(02)00114-3
15
K. A. Ibrahim, Arabian Journal of Chemistry, Synthesis and characterization of polyaniline and poly(aniline-co-o-nitroaniline) using vibrational spectroscopy, 10; S2668-S2674 (2017)

Ibrahim, K. A., Synthesis and characterization of polyaniline and poly(aniline-co-o-nitroaniline) using vibrational spectroscopy, Arabian Journal of Chemistry 10:S2668-S2674 (2017).

10.1016/j.arabjc.2013.10.010
16
Y. Kaitsuka, N. Hayashi, T. Shimokawa, E. Togawa and H. Goto, Polymers, Synthesis of polyaniline (PANI) in nano-reaction field of cellulose nanofiber (CNF), and carbonization, 8(2); 40 (2016)

Kaitsuka, Y., Hayashi, N., Shimokawa, T., Togawa, E., and Goto, H., Synthesis of polyaniline (PANI) in nano-reaction field of cellulose nanofiber (CNF), and carbonization, Polymers 8(2):40 (2016).

10.3390/polym8020040
17
S. Park, K. M. Kim, Y. Lee, Y. Jung and S. Kim, Korean Chemical Engineering Research, Preparation and electrochemical properties of PANI/TIO2 composites for supercapacitor electrodes, 50(1); 50-54 (2012)

Park, S., Kim, K. M., Lee, Y., Jung, Y., and Kim, S., Preparation and electrochemical properties of PANI/TIO2 composites for supercapacitor electrodes, Korean Chemical Engineering Research 50(1):50-54 (2012).

10.9713/kcer.2012.50.1.050
Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 51
  • No :4
  • Pages :5-12
  • Received Date : 2019-06-28
  • Revised Date : 2019-08-09
  • Accepted Date : 2019-08-12
  • DOI :https://doi.org/10.7584/JKTAPPI.2019.08.51.4.5
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