Dye Adsorption of Surface Modified Cellulose Nanofibril Foams through Polyelectrolytes Multilayering

Shin Young Park; Jinhyuk Choi; Heenae Shin; Hye Jung Youn

doi:10.7584/JKTAPPI.2022.12.54.6.155

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2022 Vol.54, Issue 6 Preview Page Next Page

Dye Adsorption of Surface Modified Cellulose Nanofibril Foams through Polyelectrolytes Multilayering 고분자전해질의 다층흡착처리된 셀룰로오스 나노피브릴 폼의 염료흡착 특성

30 December 2022. pp. 155-162

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Abstract

In this study, carboxymethylated cellulose nanofibril (CMCNF) foams were prepared through oven and freeze drying and chemically modified through the layer-by-layer (LbL) treatment of cationic (i.e., poly(diallyldimethylammonium chloride)) and anionic (i.e., poly(sodium 4-styrenesulfonate)) polyelectrolytes. The alternative adsorption of each polyelectrolyte on a CMCNF foam was confirmed by charge demand and Fourier transform infrared and energy-dispersive X-ray spectroscopic analyses. The cumulative adsorbed amount of polyelectrolytes in the freeze-dried foam increased up to two layers and reached a plateau, but the oven-dried foam exhibited a slower and gradual polyelectrolyte adsorption with the increasing layer number. The anionic dye adsorption was found superior when the cationic polyelectrolyte was adsorbed at the outermost layer of the CMCNF foam. The dye removal performance differed depending on the foam pore structure. Consequently, the surface charge of the CMCNF foam was effectively modified by the LbL treatment of polyelectrolytes, which can expand the application of the CMCNF foam in cationic or anionic dye removal.

Keywords

Cellulose nanofibrils

foam

layer-by-layer multilayering

polyelectrolyte

dye adsorbent

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Information

Publisher :Korea Technical Association of The Pulp and Paper Industry
Publisher(Ko) :한국펄프종이공학회
Journal Title :Journal of Korea TAPPI
Journal Title(Ko) :펄프종이기술
Volume : 54
No :6
Pages :155-162
Received Date : 2022-12-05
Revised Date : 2022-12-23
Accepted Date : 2022-12-26
DOI :https://doi.org/10.7584/JKTAPPI.2022.12.54.6.155

Journal of Korea TAPPI ISSN:0253-3200(Print) 펄프종이기술

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Literature Cited