All Issue

2017 Vol.49, Issue 6 Preview Page
Effect of the Surface Treatment with CNF/Oxidized Starch on the Physical Properties and the Printability of Paper

CNF/산화전분 표면처리가 종이 물성 및 인쇄적성에 미치는 영향

Im Jeong Hwang
,
Yong Kyu Lee
,
Jong Myoung Won†
황임정
,
이용규
,
원종명 †
Program of Paper Science & Engineering, Division of Forest Material Science & Engineering, College of Forest and Environmental Sciences, Kangwon National University, Chuncheon, 24341
강원대학교 산림환경과학대학 산림응용공학부 제지공학전공
†Corresponding author: E-Mail: wjm@kangwon.ac.kr
30 December 2017. pp. 102-110
PDF XML Citation
Abstract

This study was carried out to investigate the effect of the surface treatment with CNF alone and/or CNF-oxidized starch mixtures on the physical properties and printability of paper. CNF has better fluidity than the oxidized starch during coating process, and its coverage was excellent even though the small amount was applied to paper surface. The surface roughness was somewhat reduced by the formation of thin film. The bulk of the paper showed no significant change when applied in small amounts of CNF and/or oxidized starch mixtures, but decreased as the application amount exceeded 5 g/m2. The air resistance of paper was 853 seconds when it was applied with CNF only 2.35 g/m2, and it was impossible to measure the air permeability regardless of the application amount when the mixtures of oxidized starch were applied on the paper surface. The tensile strength, tear strength, bending strength and folding endurance, as well as elongation, were improved by surface treatment with CNF and/or the mixtures of CNF and oxidized starch. The dry pick strength of the surface treated paper showed the lowest value in the CNF treatment, and it was improved with the increase of oxidized starch content. The wet pick strength was poor enough to be unmeasurable until CNF was applied by 2 times, and excellent results were obtained as the amount of oxidized starch added increased.

Keywords
Cellulose nanofibrils (CNF)
oxidized starch
surface treatment
paper properties
References

Literature Cited

1
F. Herrick, R. Casebier, J. Hamilton and K. Sandberg, J. Appl. Polym. Sci.: Appl. Polym. Symp, Microfibrillated cellulose: Morphology and accessibility, 37; 797-813 (1983)

Herrick, F., Casebier, R., Hamilton, J., and Sandberg, K., Microfibrillated cellulose: Morphology and accessibility, J. Appl. Polym. Sci.: Appl. Polym. Symp. 37:797-813 (1983)

2
A. Turbak, F. Snyder and K. Sandberg, J. Appl. Polym. Sci.: Appl. Polym. Symp, Microfibrillated cellulose, a new cellulose product: Properties, uses, and commercial potential, 37; 815-827 (1983)

Turbak, A., Snyder, F., and Sandberg, K., Microfibrillated cellulose, a new cellulose product: Properties, uses, and commercial potential, J. Appl. Polym. Sci.: Appl. Polym. Symp. 37: 815-827 (1983)

3
S. Eichhorn, A. Dufresne, M. Aranguren, N. Marcovich, J. Capadona, S. Rowan, C. Weder, W. Thielemans, M. Roman, S. Renneckar, W. Gindl, S. Veigel, J. Keckes, H. Yano, K. Abe, M. Nogi, A. Nakagaito, A. Mangalam, J. Simonsen, A. Benight, A. Bismarck, L. Berglund and T. Peijs, J. Mater. Sci, Review: Current international research into cellulose nanofibres and nanocomposites, 45(1); 1-33 (2010)

Eichhorn, S., Dufresne, A., Aranguren, M., Marcovich, N., Capadona, J., Rowan, S., Weder, C., Thielemans, W., Roman, M., Renneckar, S., Gindl, W., Veigel, S., Keckes, J., Yano, H., Abe, K., Nogi, M., Nakagaito, A., Mangalam, A., Simonsen, J., Benight, A., Bismarck, A., Berglund, L., and Peijs, T., Review: Current international research into cellulose nanofibres and nanocomposites, J. Mater. Sci. 45(1):1-33 (2010)

10.1007/s10853-009-3874-0
4
P. Qvintus and H. Kangas, Cellulose nanofibrils (CNF) - A big hype or on the edge of a breakthrough, Webinar (2015)

Qvintus, P. and Kangas, H., Cellulose nanofibrils (CNF) - A big hype or on the edge of a breakthrough, Webinar (2015)

5
H. Charreau, M. Foresti and A. Vázquez, Recent Pat. Nanotechnol, Nanocellulose patents trends: A comprehensive review on patents on cellulose nanocrystals, microfibrillated and bacterial cellulose, 7(1); 56-80 (2013)

Charreau, H., Foresti, M., and Vázquez, A., Nanocellulose patents trends: A comprehensive review on patents on cellulose nanocrystals, microfibrillated and bacterial cellulose, Recent Pat. Nanotechnol. 7(1):56-80 (2013)

10.2174/187221013804484854
6
Ø. Eriksen, K. Syverud and Ø. Gregersen, Nord. Pulp Paper Res. J, The use of microfibrillated cellulose produced from kraft pulp as strength enhancer in TMP paper, 23(3); 299-304 (2008)

Eriksen, Ø., Syverud, K., and Gregersen, Ø., The use of microfibrillated cellulose produced from kraft pulp as strength enhancer in TMP paper, Nord. Pulp Paper Res. J. 23(3):299-304 (2008)

7
S. Ahola, M. Österberg and J. Laine, Cellulose, Cellulose nanofibrils - Adsorption with poly (amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive, 15(2); 303-314 (2008)

Ahola, S., Österberg, M., and Laine, J., Cellulose nanofibrils - Adsorption with poly (amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive, Cellulose 15(2):303-314 (2008)

10.1007/s10570-007-9167-3
8
T. Taipale, M. Österberg, A. Nykänen, J. Ruokolainen and J. Laine, Cellulose, Effect of microfibrillated cellulose and fines on the drainage of kraft pulp suspension and paper strength, 17(5); 1005-1020 (2010)

Taipale, T., Österberg, M., Nykänen, A., Ruokolainen, J., and Laine, J., Effect of microfibrillated cellulose and fines on the drainage of kraft pulp suspension and paper strength, Cellulose 17(5):1005-1020 (2010)

10.1007/s10570-010-9431-9
9
C. Hii, Ø. Gregersen, G. Chinga-Carrasco and Ø. Eriksen, Nord. Pulp Paper Res. J, The effect of MFC on the pressability and paper properties of TMP and GCC based sheets, 27(2); 388-396 (2012)

Hii, C., Gregersen, Ø., Chinga-Carrasco, G., and Eriksen, Ø., The effect of MFC on the pressability and paper properties of TMP and GCC based sheets, Nord. Pulp Paper Res. J. 27(2):388-396 (2012)

10.3183/NPPRJ-2012-27-02-p388-396
10
M.-P. Lowys, J. Desbrières and M. Rinaudo, Food Hydrocolloids, Rheological characterization of cellulosic microfibril suspensions - Role of polymeric additives, 15(1); 25-32 (2001)

Lowys, M.-P., Desbrières, J., and Rinaudo, M., Rheological characterization of cellulosic microfibril suspensions - Role of polymeric additives, Food Hydrocolloids 15(1):25-32 (2001)

10.1016/S0268-005X(00)00046-1
11
N. Lavoine, I. Desloges and J. Bras, J. Mater. Sci, Impact of different coating processes of MFC on barrier and mechanical properties, 49(7); 2879-2893 (2011)

Lavoine, N., Desloges, I., and Bras, J., Impact of different coating processes of MFC on barrier and mechanical properties, J. Mater. Sci. 49(7):2879-2893 (2011)

10.1007/s10853-013-7995-0
12
K. Kinnunen, T. Hjelt, E. Kenttä and U. Forsström, Thin coatings for paper by foam coating; 213-225, PaperCon. (2013)

Kinnunen, K., Hjelt, T., Kenttä, E., and Forsström, U., Thin coatings for paper by foam coating, PaperCon, pp. 213-225 (2013)

13
T. Salo, K. Dimic-Misic, P. Gane and J. Paltakari, Nord. Pulp Paper Res. J, Application of pigmented coating colours containing MFC/NFC: Coating properties and link to rheology, 30(1); 165-178 (2015)

Salo, T., Dimic-Misic, K., Gane, P., and Paltakari, J., Application of pigmented coating colours containing MFC/NFC: Coating properties and link to rheology, Nord. Pulp Paper Res. J. 30(1):165-178 (2015)

10.3183/NPPRJ-2015-30-01-p165-178
14
H. Rautkoski, H. Pajari, H. Koskela, A. Sneck and P. Moilanen, Nord. Pulp Paper Res. J, Use of cellulose nanofibrils (CNF) in coating colors, 30(3); 511-518 (2015)

Rautkoski, H., Pajari, H., Koskela, H., Sneck, A., and Moilanen, P., Use of cellulose nanofibrils (CNF) in coating colors, Nord. Pulp Paper Res. J. 30(3):511-518 (2015)

10.3183/NPPRJ-2015-30-03-p511-518
15
K. Oh, J. H. Lee, H. J. Youn and H. L. Lee, Micro-structure of coating color influenced by CMC and CNFs and its effect on drying and structure of coating layerTAPPI Internal Conference on Nanotechnology for Renewable Materials, Grenoble, France (2016)

Oh, K., Lee, J. H., Youn, H. J., and Lee, H. L., Micro-structure of coating color influenced by CMC and CNFs and its effect on drying and structure of coating layer, TAPPI Internal Conference on Nanotechnology for Renewable Materials, Grenoble, France (2016)

16
B. Nazari and D. W. Bousfield, Nord. Pulp Paper Res. J, Cellulose nanofibers influence on properties and processing of paperboard coatings, 31(3); 511-520 (2016)

Nazari, B. and Bousfield, D. W., Cellulose nanofibers influence on properties and processing of paperboard coatings, Nord. Pulp Paper Res. J. 31(3):511-520 (2016)

10.3183/NPPRJ-2016-31-03-p511-520
17
V. Kumar, D. W. Bousfield and M. Toivakka, Slot coating of nanocellulose on paperboardProceedings of PaperCon (2017)

Kumar, V., Bousfield, D. W., and Toivakka, M., Slot coating of nanocellulose on paperboard, Proceedings of PaperCon (2017)

18
M. Manninen, I. Kajanto, J. Happonen and J. Paltakari, Nord. Pulp Paper Res. J, The effect of microfibrillated cellulose addition on drying shrinkange and dimensional stability of wood-free paper, 26(3); 297-305 (2011)

Manninen, M., Kajanto, I., Happonen, J., and Paltakari, J., The effect of microfibrillated cellulose addition on drying shrinkange and dimensional stability of wood-free paper, Nord. Pulp Paper Res. J. 26(3):297-305 (2011)

19
S. M. Yong, Y. K. Lee and J. M. Won, Journal of Korea TAPPI, Improvement of paper properties by GCC-MFC composite filler, 48(4); 32-38 (2016)

Yong, S. M., Lee, Y. K., and Won, J. M., Improvement of paper properties by GCC-MFC composite filler, Journal of Korea TAPPI 48(4):32-38 (2016)

10.7584/JKTAPPI.2016.08.48.4.32
20
M. He, G. Yang, B. U. Cho, Y. K. Lee and J. M. Won, Cellulose, Effects of addition method and fibrillation degree of cellulose nanofibrils on furnish drainability and paper properties, 24(12); 5657-5669 (2017)

He, M., Yang, G., Cho, B. U., Lee, Y. K., and Won, J. M., Effects of addition method and fibrillation degree of cellulose nanofibrils on furnish drainability and paper properties, Cellulose 24(12):5657-5669 (2017)

10.1007/s10570-017-1495-3
21
K. Toven, D. Gorski and Ø. W. Gregersen, Fracture resistance of reinforced SC paper, Progress in Paper Physics Seminar; 109-112, Finland. Espoo. (2008)

Toven, K., Gorski, D., and Gregersen, Ø. W., Fracture resistance of reinforced SC paper, Progress in Paper Physics Seminar, Espoo, Finland, pp. 109-112 (2008)

22
K. Syverud, Ø. Gregersen, G. Chinga-Carrasco, Ø. Eriksen and S. J. I’Anson (ed.), Volume 2. The influence of microfibrillated cellulose, MFC, on paper strength and surface properties; 899-931, In Advances in Pulp and Paper Research, OxfordBury. Pulp and Paper Fundamental Research Society. (2009)

Syverud, K., Gregersen, Ø., Chinga-Carrasco, G., and Eriksen, Ø., The influence of microfibrillated cellulose, MFC, on paper strength and surface properties, In Advances in Pulp and Paper Research, I’Anson, S. J. (ed.), Oxford, Volume 2, Pulp and Paper Fundamental Research Society, Bury, pp. 899-931 (2009)

23
F. Richmond, M. Bilodeau, M. Paradis, P. Bennett and D. W. Bousfield, The blade coating of cellulose nanofibers suspensions on paperTAPPI Internal Conference on Nanotechnology for Renewable Materials, Vancouver, Canada (2014)

Richmond, F., Bilodeau, M., Paradis, M., Bennett, P., and Bousfield, D. W., The blade coating of cellulose nanofibers suspensions on paper, TAPPI Internal Conference on Nanotechnology for Renewable Materials, Vancouver, Canada (2014)

24
S. M. Mazhari Mousavi, E. Afra, M. Tajvidi, D. W. Bousfield and M. Dehghani-Firouzabad, Cellulose, Cellulose nanofiber/carboxymethyl cellulose blends as an efficient coating to improve the structure and barrier properties of paperboard, 24; 3001-3014 (2017)

Mazhari Mousavi, S. M., Afra, E., Tajvidi, M., Bousfield, D. W., and Dehghani-Firouzabad, M., Cellulose nanofiber/carboxymethyl cellulose blends as an efficient coating to improve the structure and barrier properties of paperboard, Cellulose 24:3001-3014 (2017)

10.1007/s10570-017-1299-5
Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 49
  • No :6
  • Pages :102-110
  • Received Date : 2017-12-04
  • Revised Date : 2017-12-21
  • Accepted Date : 2017-12-22
  • DOI :https://doi.org/10.7584/JKTAPPI.2017.12.49.6.102
Journal Informaiton Journal of Korea TAPPI Journal of Korea TAPPI
Online Submission
  • scopus
  • NRF
  • KOFST
  • crossref crossmark
  • crossref cited-by
  • crosscheck
  • orcid
Journal Informaiton Journal Informaiton - close