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2019 Vol.51, Issue 1 Preview Page
Width and Length Measurement of Cellulose Nanofibril by Nanoparticle Analyzer: Comparison with TEM Image Analysis

나노 입도 분석기를 사용한 셀룰로오스 나노섬유의 폭과 크기 측정: 투과전자현미경 이미지 분석과 비교

Woo-Yong Song
,
Soyoung Juhn1
,
Ju Hye Gwak2
,
Soo-Jeong Shin1†
,
Hyun-A Seong2‡
송우용
,
전소영 1
,
곽지혜 2
,
신수정 1†
,
성현아 2‡
Department of Wood and Paper Science, Chungbuk National University, Chungbuk, 28644
1Nature CosTech Co. Ltd., Cheongju, 28578
2Department of Biochemistry, Chungbuk National University, Chungbuk, 28644
충북대학교 목재종이과학과
1네이처코스텍
2충북대학교 생화학과
†Corresponding author: E-Mail: soojshin@cbnu.ac.kr
‡Co-corresponding Author: E-Mail: haseung@cbnu.ac.kr
28 February 2019. pp. 121-127
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Abstract

Applications of cellulose nanofibril are highly dependent on its dimension (length and width). Quick and easy methods for measuring cellulose nanofibril dimensions are critical in process quality control. A nanoparticle size analyzer (Dynamic laser scattering) was applied for cellulose nanofibril characterization and two distinct peak areas were observed as one was its width (2-50 nm) and another was its length (100-500 nm). The width and length of the nanofibril from the nanoparticle analyzer were lower than those of TEM image analysis but each samples showed a similar trend between nanoparticle analyzer and TEM image analysis. Thus, the dynamic laser scattering nanoparticle analysis is recommended as a quality control tool for cellulose nanofibril making process for estimation of its length and width.

Keywords
Cellulose nanofibrils
morphology
nanoparticle analyzer
TEM
References

Literature Cited

1
J. Y. Lee, C. H. Kim, E. H. Kim, T. U. Park, J. P. Jeun and S. Y. Kim, Journal of Korea TAPPI, Evaluation of electron beam irradiation as new pretreatment for cellulose nanofibril production, 48(4); 99-106 (2016)

Lee, J. Y., Kim, C. H., Kim, E. H., Park, T., U., Jeun, J., P., and Kim, S. Y., Evaluation of electron beam irradiation as new pretreatment for cellulose nanofibril production, Journal of Korea TAPPI 48(4):99-106 (2016).

10.7584/JKTAPPI.2016.08.48.4.99
2
N. Lavoine, I. Desloges, A. Dufresne and J. Bras, Carbohydrate Polymers, Microfibrillated cellulose - Its barrier properties and application in cellulosic materials: A review, 90(2); 735-764 (2012)

Lavoine, N., Desloges, I., Dufresne, A., and Bras, J., Microfibrillated cellulose - Its barrier properties and application in cellulosic materials: A review, Carbohydrate Polymers 90(2):735-764 (2012).

10.1016/j.carbpol.2012.05.026
3
Z. Ma, M. Kotaki and S. Ramakrishna, Journal of Membrane Science, Electrospun cellulose nanofiber as affinity membrane, 265(1-2); 115-123 (2005)

Ma, Z., Kotaki, M., and Ramakrishna, S., Electrospun cellulose nanofiber as affinity membrane, Journal of Membrane Science 265(1-2):115-123 (2005).

10.1016/j.memsci.2005.04.044
4
Y. Habibi, L. A. Lucia and O. J. Rojas, Chemical Reviews, Cellulose nanocrystals: Chemistry, self-assembly, and applications, 110(6); 3479-3500 (2010)

Habibi, Y., Lucia, L. A., and Rojas, O. J., Cellulose nanocrystals: Chemistry, self-assembly, and applications, Chemical Reviews 110(6):3479-3500 (2010).

10.1021/cr900339w
5
D. Bondeson, A. Mathew and K. Oksman, Cellulose, Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis, 13(2); 171-180 (2006)

Bondeson, D., Mathew, A., and Oksman, K., Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis, Cellulose 13(2):171-180 (2006).

10.1007/s10570-006-9061-4
6
H. Toyosaki, T. Naritomi, A. Seto, M. Matsuoka, T. Tsuchida and F. Yoshinaga, Bioscience, Biotechnology, and Biochemistry, Screening of bacterial cellulose-producing Acetobacter strains suitable for agitated culture, 59(8); 1498-1502 (1995)

Toyosaki, H., Naritomi, T., Seto, A., Matsuoka, M., Tsuchida, T., and Yoshinaga, F., Screening of bacterial cellulose-producing Acetobacter strains suitable for agitated culture, Bioscience, Biotechnology, and Biochemistry 59(8):1498-1502 (1995).

10.1271/bbb.59.1498
7
K. Watanabe, M. Tabuchi, Y. Morinaga and F. Yoshinaga, Cellulose, Structural features and properties of bacterial cellulose produced in agitated culture, 5(3); 187-200 (1998)

Watanabe, K., Tabuchi, M., Morinaga, Y., and Yoshinaga, F., Structural features and properties of bacterial cellulose produced in agitated culture, Cellulose 5(3):187-200 (1998).

10.1023/A:1009272904582
8
D. Klemm, F. Kramer, S. Moritz, T. Lindström, M. Ankerfors, D. Gray and A. Dorris, Angewandte Chemie International Edition, Nanocelluloses: A new family of nature‐based materials, 50(24); 5438-5466 (2011)

Klemm, D., Kramer, F., Moritz, S., Lindström, T., Ankerfors, M., Gray, D., and Dorris, A. Nanocelluloses: A new family of nature‐based materials, Angewandte Chemie International Edition 50(24):5438-5466 (2011).

10.1002/anie.201001273
9
A. Isogai, T. Saito and H. Fuluzumi, Nanoscale, 2011, TEMPO-oxidized cellulose nanofibers, 3(1); 71-85 (2011)

Isogai, A., Saito, T., and Fuluzumi, H., 2011, TEMPO-oxidized cellulose nanofibers, Nanoscale 3(1):71-85 (2011).

10.1039/C0NR00583E
10
G. Sim, M., N. Alam, L. Godbout and T. van de Ven, Cellulose, Structure of swollen carboxylated cellulose fibers, 22(2); 1019-1026 (2014)

Sim, G., Alam, M., N., Godbout, L., and van de Ven, T., Structure of swollen carboxylated cellulose fibers, Cellulose 22(2):1019-1026 (2014).

11
A. Naderi and T. Lindström, Nordic Pulp & Paper Research Journal, A comparative study of the rheological properties of three different nanofibrillated cellulose systems, 31(3); 354-363 (2016)

Naderi, A. and Lindström, T. A comparative study of the rheological properties of three different nanofibrillated cellulose systems, Nordic Pulp & Paper Research Journal 31(3):354-363 (2016).

10.3183/npprj-2016-31-03-p354-363
12
O. Nechyporchuk, M. N. Belgacem and F. Pignon, Biomacromolecules, Current progress in rheology of cellulose nanofibril suspensions, 17(7); 2311-2320 (2016)

Nechyporchuk, O., Belgacem, M. N., and Pignon, F., Current progress in rheology of cellulose nanofibril suspensions, Biomacromolecules 17(7):2311-2320 (2016).

10.1021/acs.biomac.6b00668
13
S. J. Chun, S. Y. Lee, G. H. Doh, S. Lee and J. H. Kim, Journal of Industrial and Engineering Chemistry, Preparation of unltrastrength nanopapers using cellulose nanofirils, 17; 521-526 (2011)

Chun, S. J., Lee, S. Y., Doh, G. H., Lee, S., and Kim, J. H., Preparation of unltrastrength nanopapers using cellulose nanofirils, Journal of Industrial and Engineering Chemistry 17:521-526 (2011).

10.1016/j.jiec.2010.10.022
14
H. Fukuzumi, T. Saito and A. Isogai, Carbohydrate Polymers, Influence of TEMPO-oxidized cellulose nanofibril length of film properties, 93(1); 172-177 (2013)

Fukuzumi, H., Saito, T., and Isogai, A., Influence of TEMPO-oxidized cellulose nanofibril length of film properties, Carbohydrate Polymers 93(1):172-177 (2013).

10.1016/j.carbpol.2012.04.069
15
Q. Wang, W. Wei, F. Chang, J. Sun, S. Xie and Q. Zhu, Bioresources, Controlling the size and film strength of individualized cellulose nanofibrils prepared by combined enzymatic pretreatment and high pressure microfluidization, 11; 2536-2547 (2016)

Wang, Q., Wei, W., Chang, F., Sun, J., Xie, S., and Zhu, Q., Controlling the size and film strength of individualized cellulose nanofibrils prepared by combined enzymatic pretreatment and high pressure microfluidization, Bioresources 11:2536-2547 (2016).

10.15376/biores.11.1.2536-2547
16
O. Kwon and S. J. Shin, Journal of Korea TAPPI, Electron microscopy for the morphological characterization of nanocellulose materials, 48(1); 5-18 (2016)

Kwon, O. and Shin, S. J., Electron microscopy for the morphological characterization of nanocellulose materials, Journal of Korea TAPPI 48(1):5-18 (2016).

10.7584/ktappi.2016.48.1.005
17
V. Dupres, C. Verbelen and Y. F. Dufrêne, Biomaterials, Probing molecular recognition sites on biosurfaces using AFM, 28(15); 2393-2402 (2007)

Dupres, V., Verbelen, C., and Dufrêne, Y. F., Probing molecular recognition sites on biosurfaces using AFM, Biomaterials 28(15):2393-2402 (2007).

10.1016/j.biomaterials.2006.11.011
18
G. Eshel, G. J. Levy, U. Mingelgrin and M. J. Singer, Soil Science Society of America Journal, Critical evaluation of the use of laser diffraction for particle-size distribution analysis, 68(3); 736-743 (2004)

Eshel, G., Levy, G. J., Mingelgrin, U., and Singer, M. J., Critical evaluation of the use of laser diffraction for particle-size distribution analysis, Soil Science Society of America Journal 68(3):736-743 (2004).

10.2136/sssaj2004.7360
19
R. Pecora, Dynamic Light Scattering: Applications of Photon Correlation Spectroscopy; 1-6, New York and London. Plenum press. (2013)

Pecora, R., Dynamic Light Scattering: Applications of Photon Correlation Spectroscopy, Plenum press, New York and London, pp. 1-6 (2013).

Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 51
  • No :1
  • Pages :121-127
  • Received Date : 2019-01-24
  • Revised Date : 2019-02-22
  • Accepted Date : 2019-02-23
  • DOI :https://doi.org/10.7584/JKTAPPI.2019.02.51.1.121
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